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The application of a photovoltaic (PV) system for zero energy buildings is crucial to balance energy consumption. This paper investigated the potential of PV systems for buildings in different climate zones of China. The tilt angle, orientation, plot ratio, PV conversion efficiency and location were selected to study their influences on electricity production. The performance of the PV system was analyzed based on a residential building, and employed RETScreen in combination with TRNSYS. The results indicate that southwest China is the best place to develop zero energy buildings. Low-rise residential buildings can realize zero energy in China when the PV conversion efficiency is higher than 20%. However, an energy balance only occurs in the southwest when the PV conversion efficiency is 10%. For different building heights, with a high conversion efficiency (20%), the energy consumptions rates are less than 15 kW h/m2a all over China. In the southeast, the effect of the building shape on energy generation can be ignored due to the high solar elevation angle in the summer. Although the optimal tilt angle varies for different cities, the energy deviations are less than 10% when tilt angle is within 10° of the optimal angle. This study proposed a formula to evaluate the potential of a building PV system. The maximum difference between the simulated and calculated results is approximately 10%, which is reasonable and acceptable. This paper provides some references for the application of PV systems in zero energy buildings. [ABSTRACT FROM AUTHOR]