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Abstract As a significant basic industry for the national economic development, coal chemical industry is one of the main contributors to energy consumption and CO 2 emission. In this paper, the CO 2 emission in the time series of 2020 and 2030 was calculated and the Logarithmic Mean Divisia Index (LMDI) method was employed to explore the driving forces of CO 2 emission change. According to the industry development, the CO 2 emission in 2020 and 2030 was tentatively predicted. The results show that China's coal chemical industry has experienced a significant increase in CO 2 emission, from 177.87 million ton CO 2 (MtCO 2) to 427.19 MtCO 2 in 2005–2015, with an average annual growth rate of 9.16%. Currently, the coal-to-ammonia industry is the largest contributor. According to the decomposition analysis, the economic growth and energy intensity are the two positive factors and the industry structure is a negative factor to carbon emission change. In 2020, the CO 2 emission will be 617.34 MtCO 2 under slow development scenario and 759.69 MtCO 2 under rapid development scenario. In 2030, the CO 2 emission will reach 1041.90 MtCO 2 and 1440.13 MtCO 2 under slow and fast development scenarios, respectively. The coal-to-olefins industry will take the place of coal-to-ammonia and turn to be the largest one in 2020 and 2030 if no CO 2 capture, utilization and storage (CCUS) technologies are adopted. It is probable that the contribution from coal-to-methanol will also play important role for CO 2 emission due to its rapid development. In addition, by 2030, if coal-to-natural gas industry develops as planned, its CO 2 emission will significantly increase, which has the potential to be equivalent to that of olefins industry. Highlights • The CO 2 emission evolution trend in China's coal chemical industry is analyzed. • The major driving factors of CO 2 emission change are identified and the effect sizes of various factors are evaluated. • The CO 2 emission in 2020 and 2030 is forecasted. • Policy implications to policymakers are provided. [ABSTRACT FROM AUTHOR]