Increased artificial constructions due to urbanization absorb more solar radiation, making urban surface and air temperatures rise and affecting the energy performance of urban buildings and the human health. Many studies have reported that green facades and roofs, materials with high albedos can noticeably reduce building surface temperatures and cool the air in summer. However, little is known about the cooling effects and assessment of different mitigation strategies when they are adopted in a block scale. This study focuses on assessing and comparing the effects in the high-rise communities in Xi’an, China, which are a good representation of the city because they are composed of a high density of buildings, and they cover the majority of the current urban sprawl land. Simulations of three community prototypes through ENVI-met software were carried out in order to assess the mitigation techniques in terms of the ground surface, building surface, and vertical canopy air temperature decrease. The main techniques adopted were cool pavements, cool coating facades and roofs, green facades with ivy and green roofs with funkia and 15 cm substrates, and combinations of those. The statistical analysis results revealed that green roof can cool the roof more than the cool roof, while cool facade can cool the facade more than green facade. As to single mitigation strategy, the cool pavement have the most significant potential to decrease canopy air temperature. In general, the combination of different strategies had much more positive effects than single solution. These positive results indicate that the cooling strategies are urgently needed in the current urban construction to alleviate the urban heat island effect.