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Using carbon dioxide (CO2) as a raw-material to produce value-added chemicals has a strategic role to play in the decarbonization of energy resources and the transition to a climate-neutral economy. E-methanol, Synthetic Natural Gas (SNG) and e-kerosene are one of the most promising pathways to convert CO2. In this context, the aim of this work is to propose an optimized and integrated CO2to methanol process and then to compare it to the CO2to SNG process from economic and environmental points of views. An optimized reactor configuration in the CO2to methanol conversion unit has been successfully implemented in Aspen Plus® and leads to a thermal energy self-sufficiency of this unit. A heat integration with an advanced capture unit has been performed where 5 % of the heat requirement could be provided from the conversion unit while 95 % come from external steam source. Techno-economic assessment of the optimized process showed that methanol is more profitable when it is used as a raw material to synthetize other chemicals. As an energy carrier, SNG is more interesting. Compared to the reference scenario, a net CO2emission reduction of 70 % in the CO2to SNG route and of 60 % in the CO2to methanol route were obtained. Concerning the fossil depletion impact, in both cases, a reduction of more than 60 % was noticed (ca. 75 % in CO2to SNG route and 61 % in CO2to methanol case).