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[Display omitted] • Carbon nanotubes can be adsorbed with liquid metal nanoparticles to form a complex (LM@CNTs) • LM@CNTs can initiate the rapid polymerization of water-soluble vinyl monomers to form hydrogel. • LM@CNTs acts as initiator, crosslinker and conductive filler simultaneously. • The resulting hydrogel exhibits excellent mechanical, adhesive and electrical performance. • Hydrogels are injectable and are expected to be used in 3D printing. Carbon nanotubes (CNTs) usually served as conductive and reinforcing nanofillers for making nanocomposites have never been reported to play a role in accelerating fabrication of hydrogels. Herein, we report an important discovery that by involving CNTs and liquid metal (LM) to form a complex (LM@CNTs), multifunctional hydrogels are rapidly prepared from vinyl monomers without heating or adding any initiators and crosslinkers. Study results demonstrate that LM@CNTs not only performs as both initiator and crosslinker for synthesizing hydrogels, but also dramatically reduces the polymerization duration from 3 days to minute levels, compared with that of only LM involved in hydrogel fabrication. Specifically, the complex initiates (<60 s) and crosslinks (<8min) monomers to form the high-performance hydrogels, which significantly reduces energy consumptions. The resulting polyacrylic acid (PAA) hydrogel possesses super stretchability (∼1200 %), high tensile strength (0.96 MPa), outstanding strain sensitivity (Gauge factor = 15.40 at 300–500 % strain), and excellent adhesion to various substrate surfaces. Additionally, the injectable molding performance will benefit the mass production of the hydrogels, which exhibits great potential for applications of wearable flexible sensors. This study provides an environmentally friendly, rapid polymerization, and energy-saving strategy by effectively applying nano-fillers for viable fabrication and application of multifunctional hydrogels. [ABSTRACT FROM AUTHOR]

[Display omitted] The active cyano-group in polyacrylonitrile has severe passivation of lithium anode under larger current density, which restricts the wide application of polyacrylonitrile(PAN) in lithium metal batteries. Herein, in order to address the excessive passivation of lithium metal by PAN, inspired by the pre-oxidation of carbon fibers, PAN was pre-oxidized at 230 °C, which transformed part of the cyano group into a more chemically stable cyclized structure. The electrochemical and mechanical properties of the composite solid electrolyte were effectively improved by introducing the fast ionic conductor Li 6.25 La 3 Zr 2 Al 0.25 O 12 into PAN by electrospinning. The oxidized PAN-based composite solid electrolyte presents high ionic conductivity (3.05 × 10−3 S·cm−1) and high lithium transference number of 0.79 at 25 °C, further contributing to a high electrochemical window (5.3 V). The solid-state batteries assembled by Li||10 wt%-LLZAO@230-oxy-PAN||NCM523 behave superb electrochemical performance, delivering a high initial discharge capacity of 157 mAh g−1 at 0.2 C. After 100 cycles, the capacity retention was 93.3 %, indicating the electrolyte displays great electrochemical stability. This work provides new insights into the structural design of polymer-based high-voltage batteries. [ABSTRACT FROM AUTHOR]

[Display omitted] Enhancing the flame retardancy of epoxy (EP) resins typically entailed a trade-off with other physical properties. Herein, hyperbranched poly(amidoamine) (HPAA) and phytic acid (PA) were used to functionalize graphene oxide (GO) via electrostatic self-assembly in water to prepare a phosphorus-nitrogen functionalized graphene oxide nanosheet (PN-GOs), which could be utilized as high efficient flame-retardant additive of epoxy resin without sacrificing other properties. The PN-GOs demonstrated improved dispersion and compatibility within the EP matrix, which resulted in significant concurrent enhancements in both the mechanical performance and flame-retardant properties of the PN-GOs/EP nanocomposites over virgin EP. Notably, the incorporation of just 1.0 wt% PN-GOs yielded a 20.4, 6.4 and 42.7 % increases in flexural strength, flexural modulus and impact strength for the PN-GOs/EP nanocomposites, respectively. Furthermore, simultaneous reductions were achieved in the peak heat release rate (pHRR) by 60.0 %, total smoke production (TSP) by 43.0 %, peak CO production rate (pCOP) by 57.9 %, and peak CO 2 production rate (pCO 2 P) by 63.9 %. This study presented a facile method for the design of GO-based nano flame retardants, expanding their application potential in polymer-matrix composites. [ABSTRACT FROM AUTHOR]

[Display omitted] To achieve rapid preparation of hydrogels without using conventional chemical initiators, a stable suspension of eutectic gallium indium (EGaIn) liquid metal nanoparticles is explored by probe-sonicating the metal in an aqueous solution. Liquid metal suspension was sonicated to serve as a photo-initiator for acrylamide polymerization and produce hydrogels. The initiation effect comes from the fact that liquid metal suspension after sonication can produce a large number of free radicals when exposed to ultraviolet (UV) radiation, leading to initiation. The changes of liquid metal nanodroplets under UV light irradiation have been systematically investigated. Further, the liquid metal colloidal solutions were used to prepare hydrogels with the same transparency and adjustable mechanical properties as the samples initiated by commercial photo-initiators. This work shows the great application potential of liquid metal in the preparation of hydrogels and provides a new technical idea for the design of multifunctional hydrogels. [ABSTRACT FROM AUTHOR]

[Display omitted] Linear polymer (e.g. polyethylene oxide, PEO) based electrolytes have been widely studied due to their flexibility and relatively good contact against electrodes. However, the linear polymers are prone to crystallization at room temperature and melting at moderate temperature, restricting their application in lithium metal batteries. To address these problems, a self-catalyzed crosslinked polymer electrolyte (CPE) was designed and prepared by the reaction of poly (ethylene glycol diglycidyl ether) (PEGDGE) and polyoxypropylenediamine (PPO) with only the bistrifluoromethanesulfonimide lithium salt (LiTFSI) added and with no any initiators. LiTFSI catalyzed the reaction by reducing the activation energy to form a crosslinked network structure, which was identified by calculation, NMR and FTIR. The as-prepared CPE has high resilience and a low glass transition temperature (Tg = −60 °C). Meanwhile, the solvent-free in-situ polymerization technique has been adopted in the assembly of the CPE with electrodes to decrease the interfacial impedance greatly and improve the ionic conductivity to 2.05 × 10−5 S cm−1 and 2.55 × 10−4 S cm−1 at room temperature and 75 °C, respectively. As a result, the in-situ LiFeO 4 /CPE/Li battery exhibits outstanding thermal and electrochemical stability at 75 °C. Our work has proposed an initiator-free and solvent-free in-situ self-catalyzed strategy of preparing high performance crosslinked solid polymer electrolytes. [ABSTRACT FROM AUTHOR]

[Display omitted] The garnet ceramic Li 6.4 La 3 Zr 1.4 Ta 0.6 O 12 (LLZTO) modified separators have been proposed to overcome the poor thermal stability and wettability of commercial polyolefin separators. However, the side reaction of LLZTO in the air leads to deterioration of environmental stability of composite separators (PP-LLZTO), which will limit the electrochemical performance of batteries. Herein, the LLZTO with the polydopamine (PDA) coating (LLZTO@PDA) was prepared by solution oxidation, and then applied it to a commercial polyolefin separator to achieve a composite separator (PP-LLZTO@PDA). LLZTO@PDA is stable in the air, and no Li 2 CO 3 can be observed on the surface even after 90 days in the air. Besides, LLZTO@PDA coating endows the PP-LLZTO@PDA separator with the tensile strength (up to 103 MPa), good wettability (contact angle 0°) and high ionic conductivity (0.93 mS cm−1). Consequently, the Li/PP-LLZTO@PDA/Li symmetric cell cycles stably for 600 h without significant dendrites generation, and the assembled Li//LFP cells with PP-LLZTO@PDA-D30 separators deliver a high capacity retention of 91.8% after 200 cycles at 0.1C. This research provides a practical strategy for constructing composite separators with excellent environmental stability and high electrochemical properties. [ABSTRACT FROM AUTHOR]

[Display omitted] Carbon nanofiber (CNF)/polycaprolactone (PCL) composites were three-dimention (3D) printed into electromagnetic interference (EMI) shielding parts. 3D-printing process led to an inhomogeneous CNFs distribution in printed composites. The special high-resistance "internal surfaces" introduced between printed threads reduced the conductivity of printed parts and resulted in characteristic secondary percolation phenomena. Meanwhile, the accelerated melt flow in nozzle oriented CNFs in composites along the printing direction, increasing the percolation threshold compared to the random arrangement. As two stage of percolation networks formed, the 3D-printed CNF/PCL parts exhibited excellent EMI shielding performance, with EMI shielding effectiveness value up to 58.7 dB. By controlling the packing density of the printed part, a large number of apertures and heterogeneous interfaces were easily introduced into the interior of parts. It promoted multiple reflection and absorption of electromagnetic waves inside the parts, and enabled adjustment of weight and shielding effectiveness. Therefore, the 3D printing enabled the flexible formation of complex porous structures. From basic materials to designed components, the 3D printing technology can facilitate the transformation of shielding materials into high performance components that are finely designed both internally and externally, making it a promising technology in the field of manufacturing lightweight, high performance EMI shielding materials. [ABSTRACT FROM AUTHOR]

[Display omitted] • Bi-MOF nanocomposites were synthesized by self-assembly in hydrothermal reaction. • Quantum dot-like magnetic metals were embedded in C matrix derived from bilayer MOFs. • The core-shell double carbon layer enhanced dielectric loss and impedance matching. • Unique nanostructures contributed to efficient and tunable absorbing properties. • The reflection loss and effective absorption bandwidth of Bi-MOF nanocomposites are adjustable through structure control. Metal-organic framework materials (MOF) have become a new generation of microwave absorption (MA) materials. However, it is still challenging to design an appropriate microstructure that can efficiently adjust the microwave absorbing characteristics. Herein, a novel bimetal-doped core-shell carbon derived from nickel-cobalt dual-ligand MOF has been successfully prepared. By changing the ratio of the second ligand, the morphology can change from sea urchin-like to rod-like and petal-like shapes, thereby regulating the final wave absorption performance of MOF derivatives. The Bi-MOF-1 exhibited strong microwave absorption (up to −70.70 dB), while Bi-MOF-2 presented broad effective absorption bandwidth (5.92 GHz). The analyses indicated that the excellent impedance matching can be attributed to the double-layer magnetic loss and multiple dielectric loss of the core-shell structure. This work provides a feasible approach for the design and preparation of functional composite structures based on MOF derivatives with controllable microwave absorbing properties. [ABSTRACT FROM AUTHOR]