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The synthesis and X-ray structural characterization of two silver(I) coordination polymers, [Ag2(bpp)2(Phdac)]·5H2O (1) and [Ag2(bpp)(HSSal)] (2), are reported, where bpp = 4,4′-trimethylene dipyridine, H2Phdac = 1,4-phenylenediacetic acid, and H3SSal = 5-sulfosalicylic acid. X-ray crystallography reveals that the structures are stabilized through hydrogen bonding interactions. The C–H⋯πand metal⋯πinteractions of aromatic molecules play a crucial role in building a layered framework. Intricate combinations of the weak non-covalent interactions have been analyzed to explore cooperativity and competitiveness in the solid-state structures. [ABSTRACT FROM AUTHOR]

A mononuclear Cu(II) compound [Cu(OAc)(2,2'-dypam)2](ClO4) (1), where HOAc and 2,2'-dypam are, respectively, acetic acid and 2,2'-dipyridylamine, has been synthesized and characterized by single crystal X-ray diffraction analysis. The cations of 1 link by N-H ··· O hydrogen bonds to form infinite 1-D zig-zag chains, which run along the b axis. Two adjacent chains along the c axis are joined by C-H ··· O hydrogen bonds to form a 2-D network. These 2-D layers are further bridged by perchlorate anions via weak anion-π interactions that act as a supramolecular glue to build the 3-D supramolecular network. Variable temperature (1.7-300 K) magnetic measurements revealed very weak intermolecular antiferromagnetic interactions at temperatures below 20 K between Cu(II) ions mediated by hydrogen bonds, C-H ··· π and π ··· π interactions. At temperatures ≥20 K, susceptibility data corresponds to isolated Cu(II) ions, indicating that the weak interactions affect the magnetism of 1 only at very low temperatures. [ABSTRACT FROM AUTHOR]

A new Co(II) complex of general formula [Co(L)2] has been synthesized from a NNO tridentate Schiff base ligand, 2-[(piperidin-2-ylmethylimino)-methyl]-phenol (L). The title complex is characterized by elemental, spectroscopic, antibacterial, and single crystal X-ray structural studies. X-Ray crystallography reveals that the complex shows a distorted octahedral geometry around the Co(II) ion. The complex was tested against several bacteria and shows good antibacterial activities against almost all of the bacteria. The interactions of the title complex with calf thymus deoxyribonucleic acid (CT-DNA) have been investigated by electronic absorption and fluorescence spectroscopy, showing that the complex interacts with CT-DNA via partial intercalation. Thermogravimetric analysis (TGA) of the complex has also been reported and the result shows that the complex is thermally stable up to 134 °C. [ABSTRACT FROM AUTHOR]