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Start Over Author "Chen, Yingying" Journal journal of coordination chemistry Publisher taylor & francis ltd

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1 results on '"Chen, Yingying"'

1. Syntheses, structures, and host-guest interactions of 2-D grid-type cyanide-bridged compounds [Zn(L)(H 2 O) 2 ][M(CN) 4 ]·3H 2 O (L =  N , N ?-bis(4-pyridylformamide)-1,4-benzene; M?=?Ni, Pd or Pt).

Author

Hu, Aiyun, Chen, Xin, Zhou, Hu, Chen, Yingying, and Yuan, Aihua

Subjects
*CRYSTAL structure, *CYANIDES synthesis, *HOST-guest chemistry, *ZINC compounds, *BENZENE, *FORMAMIDE, *MOLECULAR self-assembly, *THERMOGRAVIMETRY
Abstract

Self-assembly of Zn2+, the pillar ligandN,N?-bis(4-pyridylformamide)-1,4-benzene, and [M(CN)4]2?(M = Ni, Pd, or Pt) formed three compounds [Zn(L)(H2O)2][M(CN)4]·3H2O (1–3). Single-crystal X-ray diffraction (XRD) analysis reveals that1–3are isostructural and consist of cyanide-bridged 2-D grid-type layers built of [Zn(L)(H2O)2]2+chains cross-linked by [M(CN)4]2?units. Thermogravimetric and powder XRD analyses indicate that1has a high thermal stability and exhibits reversibility for desorption/resorption of water guest molecules. [ABSTRACT FROM AUTHOR]

Published
2013
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