1. Formation of GaN nanodots on Si (111) by droplet nitridation
- Author
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Raffaella Calarco, Hans Lüth, Ratan Debnath, R. Meijers, A. Besmehn, Eli Sutter, Toma Stoica, and Kulandaivel Jeganathan
- Subjects
Silicon ,Analytical chemistry ,chemistry.chemical_element ,Gallium nitride ,Condensed Matter Physics ,Inorganic Chemistry ,chemistry.chemical_compound ,X-ray photoelectron spectroscopy ,chemistry ,Transmission electron microscopy ,Materials Chemistry ,Nanodot ,Crystallite ,High-resolution transmission electron microscopy ,Molecular beam epitaxy - Abstract
GaN nanodots (NDs) are obtained by Ga metallic droplet formation on Si (1 1 1) substrates followed by their nitridation. The size and density of Ga droplets and GaN NDs can be controlled by varying the growth temperature within the range 514–640 °C. Atomic force microscopy (AFM) investigation of Ga droplets shows an increase in the average diameter with temperature. The average diameter of GaN NDs increases with growth temperature while their density decreases more than one order of magnitude. In addition, the formation of a GaN crystallite rough layer on Si, in-between NDs, indicates that a spreading mechanism takes place during the nitridation process. High-resolution transmission electron microscopy (HRTEM) is used for the investigation of shape, crystalline quality and surface distribution of GaN dots. X-ray photoelectron spectroscopy (XPS) results confirm that Ga droplets that are transformed into GaN NDs spread over the sample surface during nitridation.
- Published
- 2009
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