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Polyurethane/multi-walled carbon nanotube nanodielectric thin films of 25 μm thick were prepared by solution grown method. The microstructure of the nanodielectric was examined by scanning electron microscopy. The MWCNTs are observed to be dispersed in PU matrix well apart from a few of clusters. The MWCNTs/polymer nanodielectrics characterized with decrease in energy band gap and crystallinity. The analysis of dielectric properties of the composite samples of different weight ratio was studied by measuring the permittivity and tangential loss at room temperature. The frequency dependent permittivity obeys the percolation theory. Further, it has been observed that the dielectric properties of PU and PU nanodielectric are unaffected by UV-irradiation. XRD characteristics confirm the formation of PU/MWCNTs nanodielectrics. [ABSTRACT FROM AUTHOR]

Polyurethane (PU)/Polysulfone (PSF)/Multi Wall Carbon Nanotubes (CNTs) hybrid nanocomposite films were prepared by solution grown method with different wt% of functionalized CNTs. The structural and thermal properties of PU, PSF and PU + PSF + CNTs nanocomposite films were studied by various techniques such as scanning electron microscopy (SEM), X-ray diffraction (XRD), FTIR and TGA/DTG. The dispersion of CNTs in polymer was studied by SEM spectra, which indicates the presence of CNTs on the surface of the polymeric material. XRD results show the increases of crystallinity with different weight percentage of CNTs in polymer matrix. FTIR spectra reveal the position of different chemical bonds in pure and hybrid nanocomposite films. TGA and DTG show that the thermal stability of hybrid nanocomposite is better than PU and PSF due to reinforcement of CNTs in PU-PSF matrix. Surface charge decay study represents the charge stability in hybrid nanocomposite is due the localization of charge carriers in deeper traps. [ABSTRACT FROM AUTHOR]