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The objective of the study is to investigate the potential of carbide-derived carbon (CDC) for the adsorptive removal of nonionic t-octylphenoxy poly ethoxy ethanol (TX-100), anionic sodium dodecylbenzene sulfonate (SDBS) and cationic 1-hexadecylpyridinium bromide (HDPB) surfactants from water. The CDC was characterized using TEM, SEM, FTIR, BET, EDS, XPS methods and zeta potential measurements. The effects of adsorption parameters included initial surfactant concentration, contact time, temperature, and pH of the feed solution were evaluated. The adsorption capacity and mechanism were determined by modeling the isotherm, kinetic and thermodynamic data. The kinetics results demonstrated that the adsorption of the surfactant by CDC obeys the pseudo 2nd order model. The thermodynamic results have shown that surfactants adsorption by CDC is an endothermic and spontaneous process. The Sips model agreed with the adsorption isotherm data of SDBS with R2 of 0.987, while both Freundlich and Redlich-Peterson models comply well with adsorption data for TX-100 and HDPB. The hydrophobic and electrostatic interactions were found the dominant mechanisms of the adsorption of the surfactant by CDC. The adsorption capacities of CDC were found to be 442.4, 462.0 and 578.4 mg/g for SDBS, HDPB and TX-100, respectively. [ABSTRACT FROM AUTHOR]

In the present study, the adsorption behavior of ciprofloxacin (CIP) from aqueous solution onto MWCNTs/Al2O3 was studied using batch experiments. Physical characterization of MWCNTs/Al2O3 was determined by SEM, XRD, and BET. The effective parameters investigated included: initial CIP concentration, contact time, MWCNTs/Al2O3 mass, and temperature. Based on experimental results and correlation coefficients, the rate of CIP adsorption followed the pseudo-second-model kinetics. Complete compatibility of the adsorption isotherm process was achieved with the Langmuir model, and the maximum adsorption capacity reached 41.73 mg/g under the optimized conditions (pH = 7, MWCNTs/Al2O3 dose = 1.2 g/L, contact time = 60 min, initial concentration = 10 mg/L, and temperature= 45 °C). The adsorption capacities based on the Langmuir model at different temperatures, 273, 288, 303, and 318 K, were equal to 72.18, 75.92, 79.65, and 83.47 mg/g, respectively. The determined parameters of the thermodynamic studies demonstrated the endothermic and spontaneous nature of the biosorption. The mean free energy was estimated from D–R isotherm model to be 0.316–0.707 KJ/mol, which clearly proved that the adsorption experiment followed a physical process. The data suggest that MWCNTs/Al2O3 could be used as a highly effective adsorbent material with a high capacity for the removal of antibiotics from water and wastewater. [ABSTRACT FROM AUTHOR]