1. Satellite mapping of rain-induced nitric oxide emissions from soils
- Author
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Kelly Chance, Véronique Yoboué, Randall V. Martin, A. I. Modi, Lyatt Jaeglé, Daniel J. Jacob, Linda Steinberger, Luc Sigha-Nkamdjou, Corinne Galy-Lacaux, and Thomas P. Kurosu
- Subjects
Wet season ,Atmospheric Science ,010504 meteorology & atmospheric sciences ,Soil Science ,010501 environmental sciences ,Aquatic Science ,Oceanography ,Atmospheric sciences ,01 natural sciences ,Troposphere ,chemistry.chemical_compound ,Geochemistry and Petrology ,Dry season ,Earth and Planetary Sciences (miscellaneous) ,0105 earth and related environmental sciences ,Earth-Surface Processes ,Water Science and Technology ,2. Zero hunger ,Hydrology ,Ecology ,Paleontology ,Tropics ,Forestry ,15. Life on land ,Geophysics ,Deposition (aerosol physics) ,chemistry ,13. Climate action ,Space and Planetary Science ,Atmospheric chemistry ,Soil water ,Environmental science ,Nitrogen oxide - Abstract
We use space-based observations of NO2 columns from the Global Ozone Monitoring Experiment (GOME) to map the spatial and seasonal variations of NOx emissions over Africa during 2000. The GOME observations show not only enhanced tropospheric NO2 columns from biomass burning during the dry season but also comparable enhancements from soil emissions during the rainy season over the Sahel. These soil emissions occur in strong pulses lasting 1-3 weeks following the onset of rain, and affect 3 million sq km of semiarid sub-Saharan savanna. Surface observations of NO2 from the International Global Atmospheric Chemistry (IGAC)/Deposition of Biochemically Important Trace Species (DEBITS)/Africa (IDAF) network over West Africa provide further evidence for a strong role for microbial soil sources. By combining inverse modeling of GOME NO2 columns with space-based observations of fires, we estimate that soils contribute 3.3+/-1.8 TgN/year, similar to the biomass burning source (3.8+/-2.1 TgN/year), and thus account for 40% of surface NO(x) emissions over Africa. Extrapolating to all the tropics, we estimate a 7.3 TgN/year biogenic soil source, which is a factor of 2 larger compared to model-based inventories but agrees with observation-based inventories. These large soil NO(x) emissions are likely to significantly contribute to the ozone enhancement originating from tropical Africa.
- Published
- 2004
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