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A database of difficult-to-forecast natural persistent deep slab avalanches was analyzed to determine thresholds for parameters that contribute to their release in western Canada. The database included avalanche observations and weather station data. The avalanches were grouped based on their primary cause-of-release, either precipitation loading, wind loading, solar warming or air temperature warming using a multivariate classification tree, which first split using a solar warming parameter. The precipitation group had a median 24 h snowfall of 15 cm and 3 d snowfall of 38 cm at weather stations, mostly at or below treeline. These amounts were likely closer between 20-30 and 50-80 cm at alpine start zones. The wind loading group experienced the most wind-transported snow potential. The solar warming group had predicted solar warming of 5.2°C, 10 cm into the snowpack, on the days of release. The air temperature warming group experienced the highest median maximum air temperature (5°C) on the days of release. These thresholds may be useful to forecast the likelihood of similar avalanches with experienced-based forecasting or with decision aids, although many false alarms are possible. A companion paper, Part II, relates weather model data to avalanche occurrences. [ABSTRACT FROM AUTHOR]