1. High-Field Magnetization of the S=1/2 Two-Leg Spin-Ladder Antiferromagnets CuAX2 (A=Diazine, X=Halogen)
- Author
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Kouichi Okunishi, M. Hagiwara, Zentaro Honda, Masamichi Sakai, Masami Ikeda, and Shojiro Kimura
- Subjects
Diazine ,Physics ,Condensed matter physics ,Density matrix renormalization group ,Condensed Matter Physics ,Magnetic susceptibility ,Atomic and Molecular Physics, and Optics ,Magnetic field ,Magnetization ,chemistry.chemical_compound ,chemistry ,Halogen ,General Materials Science ,High field ,Spin (physics) - Abstract
We have performed magnetic susceptibility and high-field magnetization measurements on powder samples of Cu(DEP)Br2 (DEP=2,3-diethyl-pyrazine) and Cu(DMP)Cl2 (DMP=2,3-dimethyl-pyrazine) which are regarded as spin-1/2 two-leg spin-ladders in which the exchange constants are given by J ∥ along the leg and J ⊥ along the rung. The temperature dependences of magnetic susceptibilities of these compounds show a round peak at 11 and 18 K, respectively, and are compared with those calculated with a density matrix renormalization group method for α=J ∥/J ⊥=0.45–0.55. The exchange constants of the former and the latter compounds are evaluated to be \(J/k_{\rm B}=16.5~\mathrm{K}\) and \(J/k_{\rm B}=28.4~\mathrm{K}\), respectively. No magnetization at 1.3 K appears in magnetic fields of up to about 5 T for Cu(DEP)Br2 and about 14 T for Cu(DMP)Cl2, and then the magnetization increases monotonically to saturate at around 25 T and 38 T for respective compounds. Both magnetization curves are also compared with those calculated for α=0.45–0.55 using the same exchange parameter values as in the susceptibilities.
- Published
- 2012
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