1. Strong luminescence behavior of mono- and dimeric imidazoquinazolines: Swift OLED degradation under electrical current.
- Author
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Pandey, Rampal, Méhes, Gábor, Kumar, Ashish, Singh, Roop Shikha, Kumar, Amit, Adachi, Chihaya, and Pandey, Daya Shankar
- Subjects
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ORGANIC light emitting diodes , *PHOTOLUMINESCENCE , *QUINAZOLINE , *CHEMICAL derivatives , *THERMAL stability , *DENSITY functional theory - Abstract
Design and synthesis of novel mono- and dimeric quinazoline derivatives (+)-6-methyl-6-pyridin-2-yl-5,6-dihydrobenzo[4,5]imidazo[1,2- c ]quinazoline ( 1 ) and (+)-6-[(6-methyl-5,6-dihydrobenzo-[4,5]imidazo[1,2-c]quinazolin-6-yl)-pyridin-2-yl]-6-methyl-5,6-dihydro-benzo-[4,5]imidazo-[1,2- c ]quinazoline ( 2 ) have been described. Both 1 and 2 have been characterized by elemental analyses, FT-IR, 1 H and 13 C NMR, HRMS spectroscopic studies and their structures authenticated by X-ray single crystal analyses. Photophysical properties of these compounds have been studied by UV/VIS absorption and fluorescence spectroscopy and transient photoluminescence analysis in solution, powder, and non-doped (neat) and doped vacuum-deposited films. A broad emission spectrum spanning most of the visible range and good thermal stability indicated promising application of 1 and 2 as OLED emitters. Unfortunately, under current flow we observed rapid device degradation, presumably to be related to free –N H moiety in these compounds. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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