1. In-situ Overhauser-enhanced nuclear magnetic resonance at less than 1 [formula omitted]T using an atomic magnetometer.
- Author
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Lee, Hyun Joon, Lee, Seong-Joo, Shim, Jeong Hyun, Moon, Han Seb, and Kim, Kiwoong
- Subjects
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NUCLEAR magnetic resonance , *POLARIZATION (Nuclear physics) , *NUCLEAR magnetic resonance spectroscopy , *MAGNETOMETERS , *NITROXIDES , *SIGNAL-to-noise ratio - Abstract
Graphical abstract Highlights • The first in-situ Overhauser-enhanced nuclear magnetic resonance experiment using an atomic magnetometer at ultra-low field. • Signal-to-noise ratio was 32 after sixteen averages. • On the Larmor precession of 1 H spins, a decaying oscillation was superimposed. • We attribute it to a transient 87 Rb spin precession in response to a non-adiabatic field variation. • Atomic magnetometry technique shows a new capability of zero and ultralow-field NMR. Abstract The development of atomic magnetometers has led to nuclear magnetic resonance (NMR) in zero and ultralow magnetic fields without using cryogenic sensors. However, in-situ detection, meaning that a sample locates in the detection space beside a vapor cell, has been conducted only with parahydrogen-induced polarization. Other hyperpolarization techniques remain unexplored yet. In this work, we demonstrate that Overhauser dynamic nuclear polarization allows in-situ NMR detection with an atomic magnetometer at less than 1 μ T. The 1 H NMR signal of a nitroxide radical solution was observed at 13.83 Hz, which corresponds to 325 nT. Signal-to-noise ratio was 32 after sixteen averages. On the Larmor precession of 1 H spins, a decaying oscillation was superimposed. We attribute it to a transient 87 Rb spin precession in response to a non-adiabatic field variation. This work shows a new capability of zero- and ultralow-field NMR. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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