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Highlights • Ti 3 SiC 2 encapsulated by magnetic Ni 0.5 Zn 0.5 Fe 2 O 4 shell were successfully prepared. • Moderated complex permittivity for the Ni 0.5 Zn 0.5 Fe 2 O 4 /Ti 3 SiC 2 was achieved. • Desirable higher complex permeability for the Ni 0.5 Zn 0.5 Fe 2 O 4 /Ti 3 SiC 2 was realized. • The Ni 0.5 Zn 0.5 Fe 2 O 4 /Ti 3 SiC 2 coating with wide bandwidth (RL <-10 dB) of 5.3 GHz. Abstract Ti 3 SiC 2 particles encapsulated by Ni 0.5 Zn 0.5 Fe 2 O 4 shell were in-situ synthesized via a facile sol-gel method. Effects of Ni 0.5 Zn 0.5 Fe 2 O 4 shell on electromagnetic properties of Ti 3 SiC 2 were investigated in 2–18 GHz. Moderated complex permittivity and desirable higher complex permeability presented for the Ni 0.5 Zn 0.5 Fe 2 O 4 /Ti 3 SiC 2 composite, resulting in strong microwave attenuation ability and good impedance matching property. The measured effective absorbing bandwidth (RL < −10 dB) of 5.3 GHz and corresponding maximum RL of −38.6 dB were obtained for the Ni 0.5 Zn 0.5 Fe 2 O 4 /Ti 3 SiC 2 absorbing coating of 1.2 mm thickness. These results indicate that the Ni 0.5 Zn 0.5 Fe 2 O 4 /Ti 3 SiC 2 composite may become a new type of microwave absorbent. [ABSTRACT FROM AUTHOR]

• Magnetic CoNi-wrapped Ti 3 SiC 2 composites were successfully prepared. • Obvious regulated electromagnetic parameters for the composites can be realized. • The EAB of 4.88 GHz and optimal RL value of −41.41 dB were achieved. The magnetic–dielectric composites with synergetic magnetic and dielectric losses have exhibited great potential in the practical applications of microwave absorbing material. This paper reports a simple low-temperature in situ hydrothermal approach for synthesizing novel composites composed of the dielectric Ti 3 SiC 2 wrapped with magnetic CoNi nanoparticles. The microstructure, morphology, electromagnetic properties, and microwave absorption performance of as-synthesized samples were investigated. By adjusting the content of formed magnetic CoNi nanoparticles on the surface of Ti 3 SiC 2 , obvious regulated frequency-dependence of electromagnetic parameters for the proposed CoNi/Ti 3 SiC 2 composites can be realized. Consequently, the effective absorption bandwidth (RL < −10 dB) and optimal reflection loss value of CoNi/Ti 3 SiC 2 -40 composites under thinner thickness of 1.55 mm can reach up to 4.88 GHz and −41.41 dB, respectively. Exceptional microwave absorption performance of the CoNi/Ti 3 SiC 2 composites is attributed to its simultaneously improved attenuation characteristics and optimized impedance matching, and thus can be undoubtedly identified as high-efficiency microwave absorbing material. [ABSTRACT FROM AUTHOR]