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The multi-scale chemical composition distribution and microstructure of Alloy 52M overlay on low alloy steel by hot wire plasma arc cladding (HWPC) were characterized. Stress corrosion cracking (SCC) growth rates were quantified in the dilution zone (DZ) near the fusion boundary and in the bulk of Alloy 52M using compact tension samples with a thickened cladding overlay. The DZ of the Alloy 52M side exhibited a single macroscopic dilution zone containing approximately 27-28 wt.% Cr and 50 wt.% Ni, in contrast to the multiple dilution zones observed in the DZ of Alloy 52M overlays or joints prepared using other welding technologies such as submerged arc welding (SMAW). The DZ of the HWPC overlay exhibited less dilution of Cr and Ni compared to SMAW weldment. This resulted in a shorter average SCC band and fewer local intergranular cracks in the DZ of HWPC, as observed from SCC crack growth rate specimens tested in simulated PWR primary water at 325 °C and 350 °C. These findings highlight the advantages of utilizing HWPC to enhance SCC resistance in the DZ of Alloy 52M overlays over conventional cladding technologies.