1. Facile fabrication of Zr2Ni1Cu7 trimetallic nano-alloy and its composite with Si3N4 for visible light assisted photodegradation of methylene blue.
- Author
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Sharma, Gaurav, Kumar, Amit, Sharma, Shweta, Naushad, Mu., Ahamad, Tansir, Al-Saeedi, Sameerah I., Al-Senani, Ghadah M., Al-kadhi, Nada S., and Stadler, Florian J.
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NANOFABRICATION , *METALLIC composites , *ALLOYS , *VISIBLE spectra , *PHOTODEGRADATION , *METHYLENE blue - Abstract
Abstract Novel Zr 2 Ni 1 Cu 7 trimetallic nano-alloy (TNA) and Zr 2 Ni 1 Cu 7 /Si 3 N 4 trimetallic nano-alloy composite (TNAC) have been successfully prepared by facile microwave reduction method. The synthesis of TNA and TNAC was ascertained by characterizing them by using various techniques such as SEM, TEM, XRD, EDX and FTIR etc. The EDX shows the presence of all constituents in TNA and TNAC. The XRD study demonstrated the crystalline and semi-crystalline nature of TNA and TNAC. The optical band gap study revealed that TNAC (2.47 eV) has lower band gap then TNA (2.54 eV). The visible light photocatalytic activity of Zr 2 Ni 1 Cu 7 TNA and Zr 2 Ni 1 Cu 7 /Si 3 N 4 TNAC has been successfully utilized for the photodegradation of methylene blue (MB). The presence of H 2 O 2 has been found to influence the photodegradation rate. Photodegradation results presented that maximum degradation was observed in the presence of H 2 O 2 and Zr 2 Ni 1 Cu 7 TNAC (92%). Scavenging activity has revealed that the hydroxyl radicals were the major reacting species. These species successfully degraded the MB into various intermediates that has successfully been determined by the LC-MS. Kinetic studies indicated that the degradation of MB by Zr 2 Ni 1 Cu 7 TNA and Zr 2 Ni 1 Cu 7 /Si 3 N 4 TNAC followed pseudo-first-order kinetics. Graphical abstract Unlabelled Image Highlights • Zr 2 Ni 1 Cu 7 TNA and Zr 2 Ni 1 Cu 7 /Si 3 N 4 TNAC synthesized by facile microwave reduction method. • Synthesis of TNA and TNAC were ascertained by characterizing them with SEM, TEM, XRD, EDX and FTIR. • The optical band gap study revealed that TNAC(2.47 eV) has lower band gap then TNA (2.54 eV) • TNA and TNAC were successfully employed for the photodegradation of methylene blue. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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