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Start Over Author "Serrano, Oracio" Journal journal of molecular structure

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1. Synthesis, structural characterization, and activity on the transfer hydrogenation reaction of dimesitylacetonate piano stool organometallic complexes of Ru(II), Rh(III), and Ir(III).

Author

Ibarra-Vázquez, M. Fernanda, Alvarado-Rodríguez, José G., Esqueda, Ana C., Rangel-Salas, I. Idalia, and Serrano, Oracio

Subjects
*TRANSFER hydrogenation, *HYDROGENATION, *RHODIUM compounds, *MICROWAVE heating, *PIANO, *CATALYTIC activity, *MAGNITUDE (Mathematics)
Abstract

A new small family of Ru, Rh, and Ir piano-stool complexes partially containing the bulky acac diMes , p -Cymene and Cp* ligands was synthetized and characterized. Their catalytic activity in transfer hydrogenation reaction was tested. The turn over frequency (TOF) values for aromatic- and alkyl-ketones giving the corresponding desired alcohols were increased in two orders of magnitude by using microwave heating compared with conventional thermal method. Ru, Rh and Ir β-Dimesitylaceonate piano stool complexes were used as catalytic precursors on the transfer hydrogenation reaction; the microwave irradiation heating raise the TOF values in two order of magnitude comparing with the thermal conditions. Image 1 [ABSTRACT FROM AUTHOR]

Published
2019
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