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Start Over Author "Stephen M. Read" Journal journal of organometallic chemistry
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1. Intra- vs. intermolecular configurations in the three-legged, piano-stool compounds (o, m and p-xylene)Mo(CO)3

Author

Arnold L. Rheingold, Demartino Michael P, and Stephen M. Read

Subjects
Inorganic Chemistry, chemistry.chemical_compound, Crystallography, chemistry, Stereochemistry, Organic Chemistry, Intermolecular force, Materials Chemistry, Physical and Theoretical Chemistry, Ring (chemistry), Biochemistry, p-Xylene
Abstract

The three (η6-xylene)Mo(CO)3 complexes have been prepared and crystallographically characterized to determine the rotational relationship of the arene ring to the undercarriage, as has been suggested by theoretical studies. In fact, no such relationship can be seen, especially when combined with eight examples of structures with Z′ > 1, where both staggered and eclipsed forms are found.

Published
2006
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