Search

Fly-ash particles comprising spheroidal carbonaceous particles (SCP) and inorganic ash spheres (IAS), produced from industrial fossil-fuel combustion, are found in lake sediments throughout the world where they provide an historical record of atmospheric pollutant deposition. These particles have been widely used to assess the temporal and spatial distribution of industrial atmospheric pollution in both freshwater and terrestrial environments in Europe and the USA. However, there have been very few palaeolimnological fly-ash studies undertaken in Japan and none in Japanese mountain lakes. Here, we present the historical SCP and IAS records from a radiometrically dated sediment core taken from Lake Akagi-konuma (36°31′ 54″N, 139°11′ 32″E; elevation 1,470 m) located 100 km north-west of Tokyo. Meteorological data and back trajectory analyses confirm potential sources both within Japan and further afield in China and South Korea. SCP contamination began in the 1950s and increased rapidly to a peak in the mid-1980s. It is thought this represents contamination of Japanese origin, principally oil-fired power stations within 150 km of the lake. The profile of IAS, almost solely coal-derived, shows a rapid increase in the 1970s, in contrast to the record of coal consumption in Japan. The IAS record is therefore thought to reflect long-range transport from coal combustion sources in eastern China which started to expand in the 1970s. This raises concerns over the potential impact on Japanese mountain areas from recent rapid increases in, and predicted acceleration of, emissions from this industrial process. The scale of SCP contamination recorded in Lake Akagi-konuma is equivalent to moderately impacted mountain lakes in Europe, but is at the upper end of the range for remote lakes in the western United States. [ABSTRACT FROM AUTHOR]

Spheroidal carbonaceous fly-ash particles (SCPs) are produced by the high temperature combustion of fossil-fuels such as coal and oil. They are not produced by any natural processes and therefore are unambiguous indicators of atmospheric deposition from power generation and other industrial sources. In lake sediments, SCP concentration profiles are robust, replicable and often regionally characteristic such that the main profile features can be used for sediment dating. Previous work in the UK provided dates for the three main SCP profile features for Scotland, North Wales and Northern Ireland and also highlighted the lack of information for the rest of the UK. In this study, archived SCP data and new SCP concentration profiles were compiled from 80 radionuclide-dated sediment cores from across the whole of the UK in order to determine the regional coherence of temporal trends. Using SCP cumulative percentage profiles, with the SCP concentration peak set as 100%, dates for each 10% were produced for each core. Comparing these dates, eight distinct regions were found within the UK and dated cumulative profiles, with errors, were determined for each. Despite this regionality, the whole of the UK showed the same date for the start of the record (1850±25 years) and for the 40- and 50% (1940±15 and 1955±15, respectively). The national coherence of the former is thought to be due to the large confidence limits in the radionuclide dates for this period, whilst the latter is thought to be due to the impact from the major increase in electricity demand following the Second World War and the widespread introduction and use of cheap fuel-oil. Since the 1960s the trend has been one of increasing regionalisation resulting from the introduction of particle arrestor technology, the decline of heavy industry, the move to fewer and larger sources, particularly power stations, and an increase in accuracy for the dates of recent horizons. Regional trends are seen to compare well with industrial development in the UK and in some western areas influenced by emissions from Ireland. Areas of uncertainty remain in South Wales and the northern isles. A cumulative percentile was also calculated for each region for 1963 in order that this can be compared with the 241Am and 137Cs peaks. [ABSTRACT FROM AUTHOR]

Spheroidal carbonaceous particles (SCPs) from the high temperature combustion of fossil-fuels are stored in lake sediments and provide an unambiguous record of industrially derived atmospheric contamination. It has been assumed that a single sediment core provides an accurate representation of SCP accumulation but to date there have been no studies to determine within-lake variability of the SCP sediment record. This paper describes the SCP profiles of ten sediment cores taken from the deep water area of Loch Coire nan Arr, a remote lake in north-west Scotland, UK. Although each core shows the basic SCP profile used for sediment dating in the UK there is considerable variation between cores. The conversion of SCP concentrations to cumulative percentages resolves a great deal of this variation with the result that more accurate cross-correlation and hence date allocation is possible, especially in the post-1945 section of the cores. However, significant departures from the usual SCP profile still reduce the effectiveness of this approach. It is concluded that: (i) SCP profiles from single cores from the deepest areas of the lake usually provide an accurate representation of the historical record of atmospherically deposited pollutants and that inter-core variability or noise does not affect the temporal interpretation of that profile, and (ii) comparisons of total SCP inventories are a better way of comparing historical deposition between sites as the impact of temporary variability is considerably reduced. [ABSTRACT FROM AUTHOR]