1. MolecularDistances Determined with Resonant VibrationalEnergy Transfers.
- Author
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Chen, Hailong, Wen, Xiewen, Li, Jiebo, and Zheng, Junrong
- Subjects
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ENERGY transfer , *INTERMOLECULAR interactions , *RESONANCE , *AQUEOUS solutions , *X-ray diffraction - Abstract
In general, intermolecular distancesin condensed phases at theangstrom scale are difficult to measure. We were able to do so byusing the vibrational energy transfer method, an ultrafast vibrationalanalogue of Förster resonance energy transfer. The distancesamong SCN–anions in KSCN crystals and ion clustersof KSCN aqueous solutions were determined with the method. In thecrystalline samples, the closest anion distance was determined tobe 3.9 ± 0.3 Å, consistent with the XRD result. In the 1.8and 1 M KSCN aqueous solutions, the anion distances in the ion clusterswere determined to be 4.4 ± 0.4 Å. The clustered anion distancesin aqueous solutions are very similar to the closest anion distancein the KSCN crystal but significantly shorter than the average aniondistance (0.94–1.17 nm) in the aqueous solutions if ion clusteringdid not occur. The result suggests that ions in the strong electrolyteaqueous solutions can form clusters inside of which they have directcontact with each other. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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