1. Layered tin dioxide microrods
- Author
-
Gong Jiangfeng, Shaoguang Yang, Xiaoning Zhao, Hongbo Huang, Junhong Duan, and Guangxu Cheng
- Subjects
Acoustics and Ultrasonics ,Chemistry ,Scanning electron microscope ,Tin dioxide ,Condensed Matter Physics ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Crystallography ,symbols.namesake ,chemistry.chemical_compound ,Electron diffraction ,Transmission electron microscopy ,symbols ,Selected area diffraction ,Raman spectroscopy ,High-resolution transmission electron microscopy ,Powder diffraction - Abstract
Single-crystalline layered SnO2 microrods were synthesized by a simple tin?water reaction at 900??C. The structural and optical properties of the sample were characterized by x-ray powder diffraction, energy-dispersive x-ray spectroscopy, scanning electron microscopy, high resolution transmission electron microscopy, Raman scattering and photoluminescence (PL) spectroscopy. High resolution transmission electron microscopy studies and selected area electron diffraction patterns revealed that the layered SnO2 microrods are single crystalline and their growth direction is along [1 1 0]. The growth mechanism of the microrods was proposed based on SEM, TEM characterization and thermodynamic analysis. It is deduced that the layered microrods grow by the stacking of SnO2 sheets with a (1?1?0) surface in a vapour?liquid?solid process. Three emission peaks at 523, 569 and 626?nm were detected in room-temperature PL measurements.
- Published
- 2007