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Nickel ferrite owns a lot of advantages as electrode materials for supercapacitor, such as high energy density and excellent theoretical capacity. Whereas, the electrochemical performances of NiFe 2 O 4 in terms of rate performance and cycle stability are not satisfactory due to the low conductivity. While carbon fiber is a kind of material with high conductivity. Hence, NiFe 2 O 4 @ slit modified hollow carbon fiber is obtained through the coaxial electrospinning method. The slits on hollow carbon fibers are beneficial to the contact of inner NiFe 2 O 4 nanoparticles with electrolyte. Results of electrochemical tests show that at a current density of 1 A/g, the specific capacitance of NiFe 2 O 4 @ slit modified hollow carbon fiber is calculated to be 225.4 F/g, higher than that of NiFe 2 O 4 nanoparticles of 134.8 F/g. Moreover, a better cycle and rate performances (100 % vs 80 %; 71.9 % vs 47.5 %) are achieved. This work displays that slit modified hollow carbon fiber can improve the electrochemical performance of NiFe 2 O 4 efficiently. [Display omitted] • Carbon fibers are introduced to enhance the rate and cycle performances of NiFe 2 O 4. • Slits are obtained utilizing Al 2 O 3 sacrificial hard templates. • Slits are beneficial to the contact of NiFe 2 O 4 and electrolyte. [ABSTRACT FROM AUTHOR]