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The effectiveness of methyl phenyl carbonate and diphenyl carbonate as electrolyte additives either singly or in combination with methylene methyl disulfonate and tris(-trimethyl-silyl)-phosphite has been systematically investigated in LiNi 0.8 Mn 0.1 Co 0.1 O 2 /graphite pouch cells. Experiments conducted included ultrahigh precision coulometry, electrochemical impedance spectroscopy, automated storage, gas evolution measurements as well as long-term cycling. The results showed that adding methyl phenyl or diphenyl carbonate increases the coulombic efficiency, reduces charge end-point capacity slippage rate, decreases the self-discharge rate during storage and improves the capacity retention during long-term cycling compared to cells with control electrolyte [1 M LiPF 6 ethylene carbonate:ethyl methyl carbonate 3:7] or control electrolyte with 2% vinylene carbonate. 1% diphenyl carbonate appears to be the best among the systems studied. Based on these experiments, diphenyl carbonate seems to be a very beneficial additive for improving the performance of high voltage LiNi 0.8 Mn 0.1 Co 0.1 O 2 /graphite pouch cells. [ABSTRACT FROM AUTHOR]

Designing flow fields that can lead to uniform distributions of reactants at a minimum pump work is critical to enhancing the performance of redox flow batteries. This paper reports on an improved design of conventional serpentine flow fields, in which the channel depth is linearly reduced from the inlet to the outlet, speeding up the flow speed along the flow path and enhancing the under-rid convection downstream toward the outlet. Three-dimensional numerical simulations reveal that the optimized gradient at 25% (the channel-depth ratio between the outlet and inlet) can lead to the highest pump-based voltage efficiency. Experimental validations demonstrate that the application of the optimized flow field to a vanadium redox flow battery leads to significant improvements in both energy efficiency and electrolyte utilization, which is 5.0% and 27.7%, respectively, higher than that with the conventional serpentine flow field at a relatively high current density and low flow rate (400 mA cm−2, 12 mL min−1 cm−2). The effectiveness of the flow field design in boosting the uniform reactant distribution provides a feasible approach for scaling up high-performance redox flow batteries. [Display omitted] • An improved design strategy of flow field is proposed for VRFB. • Uniform distributions of electrochemical reactants are achieved. • Energy efficiency is improved by 5.0% for optimized design. • Electrolyte utilization is improved by 27.7% compared with SFF. • Operating with optimized current density and flow rate is evaluated. [ABSTRACT FROM AUTHOR]

Polymer-based aqueous redox flow batteries (RFBs) have emerged as a promising technology for large-scale energy storage. The development of novel polymeric electrode materials with high aqueous solubility to enhance the capacity and stability of batteries is the foremost concern of this area, yet remains challenging. Here we describe a stable polymer-based aqueous RFB assembled in air atmosphere, which uses a low-cost anionic terpolymer (P4) as the active cathode material, N , N ′-dimethyl-4,4′-bipyridinium dichloride (MV) as the anode material, and environmentally benign aqueous NaCl solution (NaCl aq) as the electrolyte. P4 exhibits high solubility (28.8 Ah L−1) and low viscosity in 1.5 M NaCl aq. The theoretical storage capacity of such stable RFB is as high as 12 Ah L−1. At the current density of 10 mA cm−2 and over 170 consecutive cycles in air atmosphere at room temperature, the P4/MV RFB exhibits the actual energy density of 6.43 Wh L−1, the material utilization of 71.3%, Coulombic efficiency over 95%, and the average attenuation per cycle of 0.12%. [Display omitted] • An anionic terpolymer P4 is synthesized and used as cathode material for aqueous redox flow battery (RFB). • P4 exhibits the excellent solubility and low viscosity in 1.5 M aqueous NaCl solution. • P4 -based aqueous RFB assembled in air exhibits stable manner with excellent capacity and low attenuation per cycle. • The theoretical storage capacity of stable P4-based aqueous RFB is as high as 12 Ah L−1. [ABSTRACT FROM AUTHOR]

The plasmonic Ag nanoparticles match with vertically aligned N-doped TiO 2 nanotube arrays, which display improving photoelectrochemical performance. N-doped anatase nanotube arrays are fabricated firstly, and then cubic Ag nanoparticles of diameter 5 nm are deposited on TiO 2 nanotubes without organic additives at room temperature. X-ray photoelectron spectroscopy shows that the oxygen vacancies and N impurity are revealed in N-doped TiO 2 . The electrical properties of samples are investigated by systematic photoelectrochemical measurement. The charge transfer ability of TiO 2 , N-doped TiO 2 and Ag/N-doped TiO 2 is presented directly by Electrochemical impedance spectroscopy and Mott–Schottky measurement, respectively. The carrier density of Ag/N-doped TiO 2 is higher 2 orders of magnitude enhancement of TiO 2 . Furthermore, its photocurrent responds rapidly with illumination owing to fast photoelectron transport. And photocurrent density is 0.14 mA cm −2 at 1.23 V RHE , which is the highest among samples. Finally, the mechanism of improving photoelectrochemical activity is schematically displayed. The plasmonic Ag/N-doped TiO 2 composties are favorable for the separation for photoelectron-hole pairs and increasing electron transfer, leading to a considerably photoelectrochemical performance under sunlight. The modified nanotube arrays provide potential application in photoelectrochemical cell. [ABSTRACT FROM AUTHOR]

Salt cavern with a volume of hundreds of thousands of cubic meters for storing electrolyte has been considered as a promising large-scale storage technology. However, the solubility and electrochemical stability of active organic species are significantly limited in saturated brine solution. Here, an unsymmetrical two-electron viologens with high solubility in aqueous system is synthesized via a simple two-step reaction route. As a novel two-electron storage anolyte, its electrochemical properties are investigated in detail by cyclic voltammetry and rotating disk electrode voltammetry. Paired with (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) derivatives, the battery delivers an exceptionally high cell voltage of 1.63 V, an energy efficiency of ~80%, and an average 99.95% capacity retention per cycle at 30 mA/cm2. To extend in saturated brine solution, the battery also exhibits a high cell efficiency and stable cycle performance, providing a promising strategy for developing the large scale salt-cavern redox flow batteries. • An unsymmetrical two-electron storage anolyte viologens was fabricated via two successive steps. • The molecule presented a high solubility and delivered a reversible two electron reduction reaction. • An average capacity retention rate of 99.95% per cycle was retained for 200 cycles. • The battery exhibited a high coulombic efficiency (~99%) and energy efficiency (~78%) in saturated brine solution. [ABSTRACT FROM AUTHOR]