1. Two Cd(Ⅱ)/Mn(Ⅱ) complexes based on multinuclear metal clusters for Fe(Ⅲ) and Cr(Ⅵ) fluorescence detection and magnetic properties.
- Author
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Fan, Xu-Dong, Yan, Yang-Tian, Zhang, Meng-Yang, Cai, Wei, Zhang, Yi-Bo, Wu, Yun-Long, Lu, Lin-Lin, Zhang, Wen-Yan, and Wang, Yao-Yu
- Subjects
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MAGNETIC properties , *COORDINATION polymers , *FLUORESCENCE , *METAL clusters , *FLUORIMETRY , *DETECTION limit , *METAL ions - Abstract
Two novel complexes, {[Cd 3 (L) 2 (H 2 O) 2 ]·(H 2 O) 4 } n (1) and {[Mn(HL)(H 2 O) 2 ]·(H 2 O)} n (2), which are synthesized by the reaction of 3-(2, 4-dicarboxyphenyl)-4-carboxypyridine ligand with cadmium and manganese metal ions under the solvothermal method. The complex 1 is a 3D framework based upon trinuclear [Cd 3 (μ 2 -COO) 4 (μ 1 -COO) 4 (N) 2 ] SBUs, and the complex 2 is a one-dimensional metal oxygen chain based upon binuclear [Mn 2 (μ 2 -COO) 2 (μ 1 -COO) 2 (N) 2 ] SBUs. The solid fluorescence analysis of complex 1 reveals that the emission peak of 451 nm when its excitation peak is 336 nm. The fluorescence detection experiments of complex 1 showed that Fe3+, Cr 2 O 7 2− and CrO 4 2− can effectively to be detected. Furthermore, their limits of detection are 1.47 × 10−3 M, 1.31 × 10−3 M and 1.25 × 10−3 M, respectively. It has good recovery properties as a potential multifunctional fluorescence sensor. Besides, the quenching mechanism of fluorescence sensing is also discussed. In addition, the magnetic studies of complex 2 show strong antiferromagnetic interactions between its neighboring Mn(II) ions. [Display omitted] • Two novel stable complexes were constructed based on particular trinuclear and binuclear metal clusters. • Complex 1 shows high selectivity and sensitivity to detect Fe3+, Cr 2 O 7 2− and CrO 4 2− ions with low detection limit. • Complex 2 possesses antiferromagnetic interaction between its Mn (II) ions. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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