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An environment friendly nonlinear chalcogenide glass fiber with a Ge-Sb-Se core and a Ge-Se cladding is fabricated for bright broadband mid-infrared ( MIR) supercontinuum ( SC) generation. The fabricated Ge-Sb-Se/Ge-Se fiber with a core diameter of 6 μm shows zero group velocity dispersion at ~4.2 μm and ~7.3 μm. By pumping the fiber with a length of 11 cm at 4.485 μm with 330 fs pulses, we achieve a SC covering the 2.2-12 μm spectral range and with an output average power of ~17 mW. This bright broadband SC source is promising for high-resolution MIR spectroscopy. [ABSTRACT FROM AUTHOR]

High-purity Ge-As-Se and Ge-As-S chalcogenide glasses were prepared by modified physical and chemical purification techniques. Using the purified glasses, step-index fibers with a small core (~5.5 μm) and large numerical aperture (~1.3) were fabricated. When a 13.5-cm-long fiber was pumped with 320 fs pulses at a repetition rate of 10.5 MHz at 4.1 μm, supercontinuum spanning from ~1.8 to ~9.8 μm with a dynamic range of ±10 dB and an average power of ~3 mW was generated. [ABSTRACT FROM AUTHOR]