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1. A first transition series pseudotetrahedral oxynitride anion: synthesis and characterization of Ba(2)VO(3)N.

Author

Clarke SJ, Chalker PR, Holman J, Michie CW, Puyet M, and Rosseinsky MJ

Abstract

Ammonolysis of reactive oxide precursors affords the vanadium(V) phase Ba(2)VO(3)N that is shown by X-ray and neutron powder diffraction and Raman spectroscopy to contain pseudotetrahedral VO(3)N(4-) anions. This is the first example of such species for the first transition series metals.

Published
2002
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