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Start Over Author "Sullivan, Philip" Journal journal of the american chemical society
3 results on '"Sullivan, Philip"'

1. Theory-guided design and synthesis of multichromophore dendrimers: An analysis of the electro-optic effect

Author

Sullivan, Philip A., Rommel, Harrison, Yi Liao, Olbricht, Benjamin C., Akelaitis, Andrew J.P., Firestone, Kimberly A., Jae-Wook Kang, Jingdong Luo, Davies, Joshua A., Dong Hoon Choi, Eichinger, Bruce E., Reid, Philip J., Antao Chen, Jen, Alex K.Y., Robinson, Bruce H., and Dalton, Larry R.

Subjects
Chromophores -- Electric properties, Chromophores -- Optical properties, Chromophores -- Structure, Dendrimers -- Structure, Dendrimers -- Optical properties, Dendrimers -- Electric properties, Electrooptics -- Research, Chemistry
Abstract

The investigation of multichromophore-containing electro-optic dendritic material demonstrates that the frequently observed asymptotic dependence of electro-optic activity on chromophore number density might be overcome through rational design.

Published
2007

2. Rational enhancement of second-order nonlinearity: bis-(4-methoxyphenyl) hetero-aryl-amino donor-based chromophores: design, synthesis, and electrooptic activity

Author

Davies, Joshua A., Elangovan, Arumugasamy, Sullivan, Philip A., Olbricht, Benjamin C., Bale, Denise H., Ewy, Todd R., Isborn, Christine M., Eichinger, Bruce E., Robinson, Bruce H., Reid, Philip J., Xiaosong Li, and Dalton, Larry R.

Subjects
Chromophores -- Chemical properties, Chromophores -- Structure, Molecular structure -- Research, Chemistry
Abstract

Two new highly hyperpolarizable chromophores, based on N,N-bis-(4-methoxyphenyl)aryl-amino donors and phenyl-trifluoromethyl-tricyanofuran (C[F.sub.3]-Ph-TCF) acceptor linked together through [pi]-configuration through 2,5-divinylenethienyl moieties as the bridge, are designed and synthesized. The studies have helped in understanding the effects on molecular hyperpolarizability of substituting heteroaromatic subunits into the donor groups structures.

Published
2008

3. Rational Enhancement of Second-Order Nonlinearity: Bis-(4-methoxyphenyl)hetero-aryl-amino Donor-Based Chromophores: Design, Synthesis, and Electrooptic Activity

Author

Davies, Joshua A., primary, Elangovan, Arumugasamy, additional, Sullivan, Philip A., additional, Olbricht, Benjamin C., additional, Bale, Denise H., additional, Ewy, Todd R., additional, Isborn, Christine M., additional, Eichinger, Bruce E., additional, Robinson, Bruce H., additional, Reid, Philip J., additional, Li, Xiaosong, additional, and Dalton, Larry R., additional

Published
2008
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