1. The effect of orientation of the lateral methyl substituent on the mesophase behaviour of 4-alkoxyphenylazo aryl benzoates
- Author
-
R. Saad Gamal, H. Abaza Amira, M. Naoum Magdi, and A. Fahmi Abdelgawad
- Subjects
Steric effects ,Materials science ,Aryl ,Substituent ,Mesophase ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Ring (chemistry) ,01 natural sciences ,Medicinal chemistry ,Benzoates ,0104 chemical sciences ,chemistry.chemical_compound ,Homologous series ,chemistry ,Alkoxy group ,Organic chemistry ,General Materials Science ,0210 nano-technology - Abstract
Two homologous series of 4-alkoxyphenylazo 4ʹ-(2ʺ- (and 3ʺ-) methyl-) 4ʹ-substituted benzoates (IIna–f and IIIna–f, six series each) were prepared and investigated. Within each series, the length of the terminal alkoxy group varies among 6, 8, 10 and 12 carbons, while the other terminal substituent, X, is a polar group that alternatively changes between the electron-donating CH3O, CH3, and the electron-withdrawing Br, NO2 and CN groups, in addition to the un-substituted analogue, X = H, aiming to investigate the effect of the different orientations of the methyl groups substituted on the central benzene ring, on the mesophase behaviour. The mesomorphic properties were discussed in terms of steric and polarisability effects. The mesophase stability was correlated with the polarisability anisotropy of bonds to the terminal substituent X. Comparative studies were made between the prepared isomers with each other and with the previously investigated laterally neat analogues 4-(4ʹ-alkoxyphenylazo) phen...
- Published
- 2016