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Deciphering the geochemical diversity of S-type granites is crucial for obtaining more profound insight into their petrogenesis. We therefore undertook an integrated study of whole-rock geochemistry, Sr-Nd isotopes, and zircon U-Pb-Hf isotopes for newly recognized Late Mesoproterozoic S-type granites, including two-mica-, biotite-, garnet-bearing two-mica granites, from the western Yangtze Block, South China. The crystallization ages of these granites are ca. 1040 Ma (weighted mean 206Pb/238U age = 1036.4 ± 4.5 Ma to 1042.2 ± 1.1 Ma). They are peraluminous to strongly peraluminous (A/CNK = molar ratio of Al 2 O 3 /(CaO + Na 2 O + K 2 O) = 1.02–1.67), high-K calc-alkaline rocks, and display high concentrations of normative-corundum (0.54–7.04 wt%) as well as positive correlations of A/CNK and FeOT + MgO values, which are characteristics of S-type granites. These S-type granites are characterized by enriched in Rb, Th, K, and Pb, depleted in Ba, Sr, Ti, and Eu, with negative whole-rock εNd(t) (−0.3 to −6.8) and predominantly negative zircon εHf(t) values (−8.09 to +5.70), indicating the affinity of middle-upper crustal trends and a heterogeneous metasedimentary source. Compared with the geochemical diversity of S-type granites around the world, the variably negative εNd(t) values as well as positive and negative εHf(t) values of our S-type granites may be caused by source heterogeneity and disequilibrium melting processes. More importantly, similar to typical more mafic S-type granites from the Cape Granite Suite (South Africa) and north Queensland (Australia), the high and variable FeOT + MgO contents (2.21–6.64 wt%) are significantly attributed to coupled co-entrainment of peritectic and accessory minerals (e.g., garnet, ilmenite, zircon, and monazite), evidenced by positive relationships between FeOT + MgO and TiO 2 , CaO, Zr, Th, Hf, Y, Yb, light rare earth elements (LREEs). In conjunction with the existence of coeval rift-related A-type igneous rocks, depleted asthenosphere-derived mafic rocks, marine sedimentary sequences, and subsequent extensive Neoproterozoic arc magmatism along the western Yangtze Block, we infer that the ca. 1040 Ma S-type granites studied here were produced in a continental rifting basin that was transformed into a compression setting during the Neoproterozoic. • Late Mesoproterozoic (ca. 1040 Ma) S-type granites in the western Yangtze Block. • They originated from heterogeneous metasedimentary sources. • Source heterogeneity & disequilibrium melting cause heterogeneous Nd-Hf isotopes. • Co-entrainment of peritectic and accessory minerals cause high FeOT + MgO contents. [ABSTRACT FROM AUTHOR]

It is widely accepted that granitic melts can be highly evolved, however, the effective records of this process are usually obscure, especially for the exsolution and evolution of volatiles. We present a comprehensive investigation on zircon and apatite from less to highly fractionated granites from the central Xing'an Range, NE China, in order to reveal the mineral records for the evolution processes of granitic melt. Petrographic, whole-rock and mineralogical geochemical investigations indicate that the three granites are co-magmatic and experienced different degrees of fractionation. The variations of zircon morphology, textures and geochemical compositions reflect the progressive evolution of granitic melts from volatile-undersaturated to oversaturated conditions. The significantly decreased Raman spectra intensities imply that the zircon crystals experienced increased radiation damages and hydrothermal alteration during the fractionation of granitic magma. Correspondingly, apatite textures transform from fluid-inclusion-free to fluid-inclusion-rich stage with increasing F/Cl ratios during the magmatic evolution, implying that the segregation of isolated fluid phase in the fractionating magma. Accordingly, we conclude that the textural and compositional evolution of zircon and apatite can be regarded as efficient tools for recording granitic magma evolution. • Three granitic plutons experienced different degrees of crystallization fractionation. • Zircon textures and compositions record the transition from volatile undersaturated to oversaturated. • Apatite volatile and other trace elements fingerprint the fluids exsolution from the aqueous granitic system. [ABSTRACT FROM AUTHOR]