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Abstract: The Chinese Tianshan occupies the southernmost part of the Central Asian Orogenic Belt (CAOB). High-grade metamorphic rocks are widely distributed in its central uplift zones, composing the crustal basement of the Central Tianshan Block of the Chinese Tianshan. However, the origin of the crustal basement and whether the high-grade metamorphism was associated with the Paleozoic orogeny are still unresolved. Here, we present precise LA-ICP-(MC)-MS zircon U–Pb dating and Hf isotopic data for three meta-sedimentary rocks and one orthogneiss from the Xingxingxia Complex, which represents the Precambrian basement of the Central Tianshan Block. Zircon U–Pb dating results show that the protolith age of the orthogneiss is ca. 880Ma and that the meta-sedimentary rocks consist dominantly of 0.8–1.0Ga and 1.3–2.0Ga materials with minor early Paleoproterozoic components. In combination with the zircon Hf isotopic data, it is suggested that the crustal basement of the Central Tianshan Block was formed in the early Mesoproterozoic, which is evidently different from the Archean basement formation of the Tarim Craton. We suggest that the Central Tianshan Block may have formed through a magmatic arc accretionary orogen along the continental margin of Baltica during the Mesoproterozoic. Moreover, both the meta-sedimentary rocks and the orthogneiss of the Xingxingxia Complex simultaneously suffered a metamorphic overprint at ca. 380Ma. Zircon REE and Hf isotopic data indicate that the metamorphic zircon rims were formed by new zircon overgrowths in partial melts. Geothermobarometry and average P–T calculations using THERMOCALC on the Grt–Bt gneiss yielded ca. 720–730°C and 4–6kbar, suggesting amphibolite- to granulite-facies conditions. The Late Devonian metamorphism of the Xingxingxia Complex is possibly related to orogenic low-pressure/high-temperature metamorphism in the middle or upper crust during the closure of the eastern segment of South Tianshan Ocean. Our new data, together with the occurrences of Ordovician–Silurian eclogites and HP mafic granulites along the northeastern margin of the Tarim Craton, indicate that progressive continental collisions occurred in the southern CAOB during the Paleozoic. [Copyright &y& Elsevier]

The production of new crustal material at magmatic arcs is dominated by juvenile continental crust growth through the emplacement of voluminous mantle-derived magmatic rocks. There is evidence, however, that such settings can also accommodate the burial of supracrustal material to mid/lower crustal depths resulting in the production of the new crust through metamorphism and anatexis. Investigation of migmatitic garnet- and sillimanite-bearing schists and paragneisses demonstrate that rocks exposed within the exhumed, former middle to lower crust of eastern Gangdese arc, southern Tibet, underwent sillimanite-grade metamorphism and partial melting. Monazite in the studies rocks yield 208Pb/232Th ages of ca. 72–57 Ma, which overlaps with 206Pb/238U dates from zircon rim overgrowths of ca. 73–61 Ma. Inherited zircon cores in paragneisses and adjacent low-metamorphic grade Carboniferous sedimentary rocks of the Lhasa terrane yield similar U Pb dates, with main populations at 1220–1070 Ma, 570–470 Ma, and 370–320 Ma. When combined with previously published studies, these new data demonstrate that meta-sedimentary rocks are common in the middle/lower crust of the eastern Gangdese arc and were mainly derived from Carboniferous strata of the Lhasa terrane. The Carboniferous protolith rocks were buried to deep crustal levels via thrusting during crustal shortening during Late Cretaceous (ca. 90–70 Ma) flat subduction of the Neo-Tethyan slab. Subsequent (ca. 70–60 Ma) mantle-derived magmatism induced by slab rollback, likely facilitated metamorphism and anatexis of the sedimentary rocks in the arc. This study provides important new information on the origin of the meta-sedimentary rocks and on how they affected the evolution of the eastern Gangdese arc during the Late Cretaceous to Early Cenozoic. • 73–57 Ma sillimanite-grade meta-sedimentary rocks occur in the eastern Gangdese arc. • The meta-sedimentary rocks derived from the Carboniferous strata of the Lhasa terrane. • Crustal shortening and thrusting delivered the sedimentary rocks to the deep arc crust. • Melting of sedimentary rocks contribute to contemporaneous magmatism. [ABSTRACT FROM AUTHOR]

The Chinese Tianshan in the southwestern part of the Central Asian Orogenic Belt (CAOB) is characterized by a variety of high-grade metamorphic rocks, which provide critical constraints for understanding the geodynamic evolution of the CAOB. In this paper, we present detailed petrological and zircon U–Pb geochronological studies of the Weiya low-pressure and high-temperature (LP-HT) granulites of the Chinese Eastern Tianshan. These granulites were previously considered to be a product of a regional metamorphic orogenic event. Due to different bulk-rock chemistries the Weiya granulites, which occur as lenses within the contact metamorphic aureole of the Weiya granitic ring complex, have a variety of felsic–pelitic and mafic granulites with different textural equilibrium mineral assemblages including garnet–cordierite–sillimanite-bearing granulites, cordierite–sillimanite-bearing granulites, cordierite–orthopyroxene-bearing granulites, and orthopyroxene–clinopyroxene-bearing granulites. Average P–T thermobarometric calculations and conventional geothermobarometry indicates that the Weiya granulites underwent early prograde metamorphism under conditions of 600–650 °C at 3.2–4.2 kbar and peak metamorphism of 750–840 °C at 2.9–6.3 kbar, indicating a rather high geothermal gradient of ca. 60 °C/km. Zircon U–Pb LA–ICP–MS dating revealed metamorphic ages between 244 ± 1 to 237 ± 3 Ma, which are in accordance with the crystallization age of the Weiya granitic ring complex. We suggest that the formation of the Weiya granulites was related to contemporaneous granitic magmatism instead of a regional metamorphic orogenic event. In addition, a Late Devonian metamorphic age of ca. 380 Ma was recorded in zircon mantle domains from two pelitic samples which is consistent with the metamorphic age of the Xingxingxia metamorphic complex in the Chinese Eastern Tianshan. This suggests that the mantle domains of the zircon grains of the Weiya granulites probably formed during the Late Devonian regional metamorphism and were overprinted by the Early Triassic contact metamorphism. Therefore, Early Triassic geodynamic models for the southwestern part of the CAOB, which are based on a previously suggested regional metamorphic orogenic event of the Weiya granulites, need to be viewed with caution. [ABSTRACT FROM AUTHOR]

Numerous microcontinents are known to occur in the Central Asian Orogenic Belt (CAOB), one of the largest accretionary orogens and the most significant area of Paleozoic crustal growth in the world. The evolution of the Precambrian crust in these microcontinents is central to understanding the accretionary and collisional tectonics of the CAOB. Here, we present systematic zircon U–Pb dating and Hf isotope studies of Mesoproterozoic gneissic granitoids from the eastern Central Tianshan Arc Terrane (CTA) of the southern CAOB. The investigated intermediate to felsic (SiO 2 = 60.48–78.92 wt.%) granitoids belong to the calcic- to calc-alkaline series and usually have pronounced negative Nb, Ta and Ti anomalies, relative enrichments of light rare earth elements (LREEs) and large ion lithophile elements (LILEs) while heavy rare earth elements (HREEs) and high field strength elements (HFSEs) are depleted, revealing typical active continental margin magmatic arc geochemical characteristics. These spatially-distant rocks show consistent zircon U–Pb crystallization ages from ca. 1.45 to 1.40 Ga and thus constitute a previously unknown Mesoproterozoic continental magmatic arc covering hundreds of kilometers in the eastern segment of the CTA. Furthermore the high and mainly positive zircon ε Hf ( t ) values between − 1.0 and + 8.6 and the zircon Hf model ages of 1.95 to 1.55 Ga, which are slightly older than their crystallization ages, suggest that they were mainly derived from rapid reworking of juvenile material with a limited input of an ancient crustal component. Therefore, the formation of these granitoids defines an extensive Mesoproterozoic intermediate to felsic, subduction-related intrusive magmatic arc activity that was active from at least 1.45 to 1.40 Ga, involving significant juvenile continental growth in the eastern segment of the CTA. Furthermore the zircon U–Pb and Hf isotopic data challenge the common belief that the CTA was part of the Tarim Craton during Paleo- to Mesoproterozoic times. However, the southern Beishan microcontinents and the CTA have similar zircon U–Pb and Hf isotopic signatures, indicating a similar Precambrian tectonothermal evolution for both. This finding provides new and important constraints on the Precambrian crustal evolution of the microcontinents in the southern CAOB. [ABSTRACT FROM AUTHOR]

Early Paleozoic volcanic–intrusive rocks in the South Qinling Belt, central China, consist of bimodal alkaline suites ranging in composition from basalt to trachyte, with an apparent scarcity of intermediate silicic components (the so-called "Daly gap"). A series of trachytic rocks have been identified in the Quanxi area of the South Qinling Belt. In this work, we combine mineralogical evidence with whole-rock major- and trace-element data, Sr–Nd–Pb isotope data, and the results of thermodynamic modeling to gain a better understanding of the petrogenesis and evolutionary process of the Quanxi trachytic rocks, as well as their compositional discontinuity with coeval mafic rocks. Our samples can be clearly classified into two lithological groups based on their phenocryst content: Group 1, phenocryst-poor trachytes (<5 vol% phenocrysts; SiO 2 = 63.91–66.13 wt%) and Group 2, trachytic tufflavas (30–45 vol% pyroclasts; SiO 2 = 53.34–59.03 wt%). All of the samples exhibit typical oceanic island basalt-like enrichment in light rare earth elements and high field strength elements, as well as marked depletion of Ba, Sr, and Ti. A cogenetic metasomatized lithosphere source for the Quanxi trachytic rocks and contemporaneous mafic rocks is indicated by their homogeneous isotopic features (ε Nd (t) = +2.3 to +3.4; initial 206Pb/204Pb = 17.92–18.69; initial 207Pb/204Pb = 15.53–15.57; initial 208Pb/204Pb = 37.96–38.99) and linear geochemical variations, with protracted fractional crystallization regarded as the key mechanism for the compositional variations among these cogenetic rocks. The results of Rhyolite-MELTS modeling predict 72%–80% crystallization involving plagioclase, pyroxene, biotite, apatite, and Fe Ti oxide, to yield the magmatic compositions from an evolved mafic progenitor to the Quanxi trachytes under conditions of low pressure (1.5–2 kbar), high H 2 O content (2–3 wt%), and high f O 2 (FMQ–0.5). Some incompatible elements in trachytic tufflavas deviate markedly from the liquid lines of descent from coeval mafic rocks to the Quanxi trachytes: this deviation is attributed to a combination of the involvement of large proportions of alkali-feldspar pyroclasts and post-magmatic hydrothermal alteration. The presence of the "Daly gap" in early Paleozoic alkaline suites can be explained by an accelerated differentiation rate (i.e., dSiO 2 /d t) in the SiO 2 -intermediate field, which is driven by the simultaneous separation of a considerable scale of SiO 2 -poor phases. • South Qinling Belt, central China, contains trachytes and trachytic tufflavas. • Trachytic rocks and contemporaneous mafic rocks had a cogenetic mantle source. • Trachytes underwent fractional crystallization from an evolved mafic progenitor. • Fractionation of SiO 2 -poor minerals resulted in the presence of "Daly gap". [ABSTRACT FROM AUTHOR]

We report here for the first time the occurrence of sapphirine-bearing granulites within the Qinling Group of the Qinling-Tongbai orogen and provide robust evidence for extreme crustal metamorphism at ultrahigh-temperature (UHT) conditions. We document the UHT indicator of sapphirine and spinel in a mafic granulite consisting of orthopyroxene, biotite, plagioclase, amphibole and rutile/ilmenite. The ferromagnesian minerals in the sapphirine-bearing granulite have high X Mg [Mg/(Mg + Fe)] (orthopyroxene X Mg = 0.84–0.95; biotite X Mg = 0.81; amphibole X Mg = 0.87–0.96). The phase equilibria modeling demonstrates that the early spinel-bearing assemblage is stable at 923–950 °C and 6.7–8.9 kbar, and the peak assemblage of Opx + Pl + Spr/Spl + Amp + Bt + Ilm (+ melt) defines a field at 922–947 °C and 8.4–10.2 kbar. Rutiles have variable Zr concentrations but mostly cluster at ca. 1,500 and 3400 ppm. Zr-in-rutile geothermometry yielded high temperatures of up to 890–940 °C. Zircon U–Pb dating of the granulite constrains the timing of the immediate post-peak and retrograde metamorphic stages as 429 ± 7 Ma and 412 ± 4 Ma, respectively. The UHT metamorphism, together with extensive occurrence of coeval magmatic suites suggests that the Tongbai orogen experienced a Paleozoic Andean-type orogeny probably derived from mid-oceanic ridge subduction of the Qinling Ocean. [ABSTRACT FROM AUTHOR]

Under the condition of paucity of mantle-derived ferromagnesian components, peritectic assemblage entrainment (PAE) model can properly explain a large variation of Fe, Mg, Ti, and Ca contents as well as positive linear trends for Ti and Ca plotted against maficity (molar Fe + Mg) exhibited by more mafic I-type granitic melts. Herein we present a comprehensive study of zircon U–Pb–Hf isotopes, whole-rock major and trace elements, and Sr–Nd isotopes for newly identified Neoproterozoic high-maficity I-type granitoids collected from the Yonglang area in the western Yangtze Block, South China, in order to evaluate PAE process acting on the petrogenesis of these more mafic granitoids. Zircon U-Pb geochronological results show that the Yonglang granitoids, including the granodiorites, monzogranites, and biotite granites, yield the weighted mean 206Pb/238U ages of ca. 850–825 Ma. They are geochemically characterized by high SiO 2 (64.63–72.62 wt.%) and K 2 O (3.49–6.59 wt.%) contents as well as variable A/CNK (0.94–1.09) and molar Fe + Mg values (0.0452–0.1210), and display a negative correlation of A/CNK and Fe + Mg, indicating an I-type affinity. Isotopically, they display negative whole-rock εNd(t) (−4.06 to−6.38) and highly evolved zircon εHf(t) values (−9.36 to +1.92) as well as old two-stage Nd model ages (1.69–1.85 Ga) and crustal Hf model ages (1608–2139 Ma), implying a crustal source. In comparison with the geochemical composition of fluid-absent experimental melts, the Yonglang I-type granitoids have Fe, Mg, Ti, and Ca contents that are too high to equilibrium with those of pure crustal melts, indicating the additional incorporation of a ferromagnesian, Ti-, and Ca-rich component into primary melts. Like the Cotoncello–Monte Capanne granitic complex in Elba Island and Verdenburg I-type granite in South Africa, the Yonglang I-type granitoids exhibit highly positive linear correlations for Ti vs. maficity and Ca vs. maficity as well as negative correlation for A/CNK vs. maficity, suggesting that these high-maficity I-type granitoids predominantly underwent the peritectic assemblage entrainment of Ca-Fe-Mg-Ti bearing minerals (e.g., clinopyroxene, plagioclase, ilmenite, etc.) during coupled melting of biotite and hornblende phases in crustal source. The process of peritectic assemblage entrainment thus play a vital role in moulding geochemical compositions of more mafic I-type granites. [Display omitted] • Newly identified Neoproterozoic high-maficity I-type granitoids were formed at ca. 850-835 Ma. • They originated from coupled melting of biotite and hornblende phases in ancient crustal source. • They predominantly underwent the peritectic assemblage entrainment (PAE) process. [ABSTRACT FROM AUTHOR]

High‑uranium (~4200 to 8500 ppm U) columbite-group minerals (CGMs) from No. 1 pegmatite at Dakalasu, the Chinese Altay orogen were used to assess the effect of metamictization on the U Pb isotopic systematics. Backscattered electron (BSE) imaging shows that the high U concentrations are due to the U in the crystal structure itself. In the rims, the part of CGM next to cracks or pores filled by titan-uranoan fluorcalciomicrolite is altered. The microlite was likely formed via a dissolution-reprecipitation process that resulted in fractionation between U and Pb and potential discordance of the U Pb isotopic systematics in the altered CGM. Raman spectroscopy indicates that the columbite samples are metamictized to various extents. However, the CGM samples dated by laser ablation – inductively coupled plasma – mass spectrometer (LA-ICP-MS) show excellent U Pb age concordance, with thirty eight out of forty analyses displaying concordant U Pb ages (229.0 ± 1.0 Ma to 228.1 ± 0.6 Ma) overlapping within analytical uncertainty (2σ). The alpha-decay doses are estimated to be 1.53 to 2.31 × 1015 α-decay events/mg, indicating that the CGMs are at a transition stage from being crystalline to completely metamict states. Although spatial separation between U and radiogenic Pb isotopes caused by α-recoil is inevitable, the displacement is on sub-micron scale, much smaller than the scale of laser ablation pits (43 μm) for LA-ICP-MS dating. Therefore, the U Pb isotopic systematics of partially metamict, U-rich CGM may still remain concordant for CGMs that have not suffered hydrothermal alteration or metasomatism and do not contain U- or Pb-rich inclusions within the laser ablation pits. Additionally, the chemical compositions of the CGM have no control over the U Pb isotopic systematics. • The effect of metamictization on columbite U Pb isotopic systematics is investigated. • The degree of metamictization is quantified using α-decay dose and displacements per atom. • Hydrothermal alteration can result in discordance of columbite U Pb isotopic systematics. [ABSTRACT FROM AUTHOR]

Deciphering the geochemical diversity of S-type granites is crucial for obtaining more profound insight into their petrogenesis. We therefore undertook an integrated study of whole-rock geochemistry, Sr-Nd isotopes, and zircon U-Pb-Hf isotopes for newly recognized Late Mesoproterozoic S-type granites, including two-mica-, biotite-, garnet-bearing two-mica granites, from the western Yangtze Block, South China. The crystallization ages of these granites are ca. 1040 Ma (weighted mean 206Pb/238U age = 1036.4 ± 4.5 Ma to 1042.2 ± 1.1 Ma). They are peraluminous to strongly peraluminous (A/CNK = molar ratio of Al 2 O 3 /(CaO + Na 2 O + K 2 O) = 1.02–1.67), high-K calc-alkaline rocks, and display high concentrations of normative-corundum (0.54–7.04 wt%) as well as positive correlations of A/CNK and FeOT + MgO values, which are characteristics of S-type granites. These S-type granites are characterized by enriched in Rb, Th, K, and Pb, depleted in Ba, Sr, Ti, and Eu, with negative whole-rock εNd(t) (−0.3 to −6.8) and predominantly negative zircon εHf(t) values (−8.09 to +5.70), indicating the affinity of middle-upper crustal trends and a heterogeneous metasedimentary source. Compared with the geochemical diversity of S-type granites around the world, the variably negative εNd(t) values as well as positive and negative εHf(t) values of our S-type granites may be caused by source heterogeneity and disequilibrium melting processes. More importantly, similar to typical more mafic S-type granites from the Cape Granite Suite (South Africa) and north Queensland (Australia), the high and variable FeOT + MgO contents (2.21–6.64 wt%) are significantly attributed to coupled co-entrainment of peritectic and accessory minerals (e.g., garnet, ilmenite, zircon, and monazite), evidenced by positive relationships between FeOT + MgO and TiO 2 , CaO, Zr, Th, Hf, Y, Yb, light rare earth elements (LREEs). In conjunction with the existence of coeval rift-related A-type igneous rocks, depleted asthenosphere-derived mafic rocks, marine sedimentary sequences, and subsequent extensive Neoproterozoic arc magmatism along the western Yangtze Block, we infer that the ca. 1040 Ma S-type granites studied here were produced in a continental rifting basin that was transformed into a compression setting during the Neoproterozoic. • Late Mesoproterozoic (ca. 1040 Ma) S-type granites in the western Yangtze Block. • They originated from heterogeneous metasedimentary sources. • Source heterogeneity & disequilibrium melting cause heterogeneous Nd-Hf isotopes. • Co-entrainment of peritectic and accessory minerals cause high FeOT + MgO contents. [ABSTRACT FROM AUTHOR]

It is widely accepted that granitic melts can be highly evolved, however, the effective records of this process are usually obscure, especially for the exsolution and evolution of volatiles. We present a comprehensive investigation on zircon and apatite from less to highly fractionated granites from the central Xing'an Range, NE China, in order to reveal the mineral records for the evolution processes of granitic melt. Petrographic, whole-rock and mineralogical geochemical investigations indicate that the three granites are co-magmatic and experienced different degrees of fractionation. The variations of zircon morphology, textures and geochemical compositions reflect the progressive evolution of granitic melts from volatile-undersaturated to oversaturated conditions. The significantly decreased Raman spectra intensities imply that the zircon crystals experienced increased radiation damages and hydrothermal alteration during the fractionation of granitic magma. Correspondingly, apatite textures transform from fluid-inclusion-free to fluid-inclusion-rich stage with increasing F/Cl ratios during the magmatic evolution, implying that the segregation of isolated fluid phase in the fractionating magma. Accordingly, we conclude that the textural and compositional evolution of zircon and apatite can be regarded as efficient tools for recording granitic magma evolution. • Three granitic plutons experienced different degrees of crystallization fractionation. • Zircon textures and compositions record the transition from volatile undersaturated to oversaturated. • Apatite volatile and other trace elements fingerprint the fluids exsolution from the aqueous granitic system. [ABSTRACT FROM AUTHOR]