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Research subject. 14 samples of limestone and one sample of carbonate-siliciclastic rock from siliciclastic-carbonate deposits of the Upper Riphean Uk Formation (the Southern Urals) were studied.Methods. Mineral and chemical composition of the samples were determined; the main tool for detecting the concentrations of trace elements was the ICPMS method. X-ray diffraction analysis was carried out using a Shimadzu XRD-7000 diffractometer, the content of major (rock-forming) oxides in bulk samples was established by X-ray fluorescence spectrometry on the SRM-35 and Shimadzu XRF 1800 spectrometers. Microelement composition of bulk samples and acidic leachates obtained with using acetic (10%), nitric (36%) and hydrochloric (17%) acids was determined on a Perkin Elmer ELAN 9000 spectrometer.Results. The distribution of lithophile, rare-earth and a number of other elements (Sr, Ni, U) both in bulk samples and in acidic leachates was analyzed. The main carrier phases of these elements were revealed.Conclusions. 1. The use of any listed acids leads to the non-carbonate component entering the solution, including contamination of the “carbonate” leachates by lithophile elements. In particular, a transition Rb, Zr, Li, Th, Ti, Sc to leachates was noted. This process is most active in nitric and hydrochloric acids, less intensive in acetic acid. 2. Among the carriers of rare earth elements (REE) in the studied rocks are clays (1), accessory minerals (2), including phosphate-bearing grains, secondary carbonate phases represented by dolomite and, possibly (3), finely disseminated iron and manganese (oxy)hydroxides (4). It is assumed that the REE pattern in limestones is determined by the content of the epigenetic dolomite. The contribution of lanthanides bound in the sedimentary calcite crystal lattice in the total REE pattern is rather large only in relatively “pure” limestones. However, the use of acids with such concentrations did not allow to obtain a leachate, which the REE pattern with high probability corresponds to the distribution of REE in the Uk time seawater. But acetic acid is more effective for achieving this goal than the others. 3. In addition to Sr, sedimentary calcite also contains Ni and U.

Research subject . In this article, we present the results of comparative mineralogical and geochemical studies of organic remains and coprolites from the Lower Triassic and Paleogene continental deposits of the Northern Urals and East Kazakhstan. Methods . The studies were conducted using a wide range of analytical methods, including optical microscopy; chemical analysis; determination of C org content; thermal and powder X-ray diffraction analysis; spectroscopy; scanning electron microscopy; X-ray fluorescence analysis; isotopic analysis gas pyrochromatography; inductively coupled plasma mass spectrometry. Results . A significant concentration of fish bones, teeth and scales, as well as coprolites of labyrinthodonts were identified in the Lower Triassic and Paleogene continental-marine terrigenous and carbonate-terrigenous sedimentary rocks of the Northern Urals and East Kazakhstan. In terms of mineral composition, the fossils and coprolites are found to be almost completely composed of B-type carbonate apatite. The phase-heterogeneous impurities in the coprolites are represented by calcite, siderite, barite, polycomponent carbonates of the MnCO 3 –FeCO 3 –MgCO 3 –CaCO 3 system and pyrite. It should be noted that pyrite demonstrates octahedral habitus, which is rather rare for this mineral. The ratio of the essential and xenobiotic elemental concentrations differs for the Lower Triassic and Paleogene coprolites, reaching 0.17 and 0.35 on average, respectively. For the first time, information has been given on the content of lithogenic gases in coprolites and the isotopic composition of the impurity carbonaceous material. According to this data, Lower Triassic labyrinthodonts could feed on plants, as well as herbivorous and carnivorous fish. Conclusion . The findings of coprolites in the Northern Urals and East Kazakhstan in a wide Meso-Cenozoic chronological range and in highly different geological settings indicate the probability of a much wider development of coprogenic-phosphate sedimentary rocks in nature than it has been previously considered. Under a high concentration of coprolites, these rocks can serve as a new and extremely valuable type of phosphorite raw materials, the utilization of which would not require any preliminary treatment.