1. Neutron Reflectivity and Computer Simulation Studies of Self-Assembled Brushes Formed by Centrally Adsorbed Star Polymers
- Author
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Nikos Hadjichristidis, D.L. Anastassopoulos, George Sakellariou, Chris Toprakcioglu, Alain Menelle, Ioannis Hiotelis, Alexandros Koutsioubas, Alexandros A. Vradis, and Nikolaos Spiliopoulos
- Subjects
chemistry.chemical_classification ,Quantitative Biology::Biomolecules ,Materials science ,Polymers and Plastics ,Organic Chemistry ,Monte Carlo method ,Polymer ,Polymer brush ,Kinetic energy ,Condensed Matter::Soft Condensed Matter ,Inorganic Chemistry ,chemistry.chemical_compound ,chemistry ,Chemical physics ,Polymer chemistry ,Materials Chemistry ,Copolymer ,Neutron ,Polystyrene ,Physics::Chemical Physics ,Scaling ,Astrophysics::Galaxy Astrophysics - Abstract
The equilibrium properties of polymer brushes formed by starlike polymers with varying number of arms attached to a surface by their center were studied experimentally with neutron reflectrometry (NR). Polystyrene (PS) stars in a good solvent (toluene) were centrally adsorbed onto a quartz substrate via a zwitterionic anchor group. Increasing the number of arms resulted in significantly lower equilibrium adsorbance, while replacement experiments of a 3-armed star brush by linear chains revealed interesting equilibrium and kinetic features related to the special architecture of star polymers. These results are compared with scaling theoretical calculations and Monte Carlo simulations of centrally adsorbed star polymers that were performed under the bond fluctuation simulation scheme. Several features of the experimental results are reproduced in our simulation study.
- Published
- 2008
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