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Although steel reinforcements are used to withstand tensile forces in concrete, cracks are an unavoidable phenomenon. The presence of cracks, in fact, increases the risk for lowering the service life and durability of concrete structures. A critical issue occurs when due to splitting forces, cracks appear in concrete along the tensioned rebars which damage the bonding between the steel and concrete matrix. As a mitigation plan, the cracks should be healed at short notice and the bonding has to be recovered by the potential use of healing agents. This paper aims to investigate the bond behaviour of steel reinforcement in self-healing concrete. Two biomasses were employed as healing agents namely HTN (bacteria-based) and YEAST (fungi-based). The fresh and hardened properties of the normal and self-healing concretes were initially evaluated. The bond properties were investigated by performing pull-out tests on three different states of concrete: uncracked, cracked, and healed. Results revealed that the additions of biomasses did not induce negative effects on the compressive strength of hardened concrete. Moreover, the average bond strength of uncracked concretes containing HTN and YEAST improved by 20% and 8%, respectively, as compared with normal concrete. The introduction of a crack caused a significant reduction in bond strength regardless of the addition of healing agents. Nevertheless, it was found that the bond strength was slightly recovered after healing under water immersion.

Extreme environments are aggressive for concrete structures, hence a performance-based design is crucial to guarantee the durability during the service life. Nonetheless, there is a knowledge gap regarding the influence of cracks on standard and self-healing concrete. This research focuses on monitoring cracked self-healing concrete with two commercial healing agents: a bacteria-based healing agent (BAS) and a crystalline admixture (CA). After crack formation and a healing process of three months in wet/dry conditions (4 days/3 days), several extreme conditions were considered: (1) submerged in artificial seawater, (2) submerged in a solution with 33 g/L sodium chloride and (3) freeze-thaw (FT) cycling with de-icing salts. Microscopic images were used to quantify the healing efficiency of the two different healing agents, while chloride ingress and scaling were measured to determine durability. The results of the microscopic measurements indicated significant healing efficiency for both healing agents after the healing regime reaching 72% for CA, and 67% for BAS. After exposure to a marine environment, this efficiency increased to 95% and 92%, respectively. The uncracked BAS samples achieved a scaling reduction of 93% under FT exposure relative to the uncracked REF samples, while this was 49% for the CA samples. In cracked samples, scaling was reduced by 50% for BAS and 24% for CA, relative to the cracked REF samples. In all tested conditions, the BAS samples partially prevented the chloride ingress through the crack, while CA samples showed a great reduction. Overall, both healing agents reduced the degradation and could decrease the chloride ingress.

As an alternative to the usage of axenic bacteria to achieve microbially induced calcium carbonate precipitation (MICP), this study evaluates the usage of two non-axenic biomasses as self-healing agents. A fungi-based consortium (Yeast) and heterotrophic nitrifiers (HTN) were harvested from the incubation of agricultural side streams. The characteristics of the two biomasses were identified through flow cytometry, total suspended solids and volatile suspended solids tests. The incorporation of the biomasses into concrete was evaluated in terms of compressive strength, flow and healing ability. Self-healing ability was analyzed through microscope imaging on prismatic (60x60x220 mm) samples. Cracks were induced with a three-point bending test where the widths were controlled with an LVDT sensor. A curing period of 56 days was applied to the samples and visual inspection was conducted at the start and end of the healing period with an optical microscope. Results compare and discuss the differing effects of active and autoclaved biomasses on the concrete properties and crack closure.

Lime-based construction materials (LBM) range from concrete blocks to mortars and plasters used in building new structures or to conserve our cultural heritage. However, little interest has been aroused in the scientific community about their sustainability assessment through Life Cycle Assessment. This research presents a case study carried out within the framework of the SUBLime Project (MSCA ETN-ITN network) and aims at contributing to the understanding of environmental and economic sustainability of LBM. Through a real case-study, a detailed Life Cycle Inventory was developed to calculate the environmental impact associated to different mixes, use of additives, aggregates, etc. Furthermore, Life Cycle Cost Assessment methodology was used to determine the share of different items in the total cost of the cradle-to-grave production of LBM. A thorough analysis of the combined environmental and economic results are presented along with suggestions regarding mix compositions, aggregates, additives, and critical processes in the production line to achieve more sustainable production of LB materials.

Bacteria-based self-healing concrete has become an effective approach to mitigate microcracks in the concrete structure. However, there are still doubts about when to use vegetative cells or spores of Bacillus sphaericus as a healing agent. Thus, this research aims to give recommendations regarding this choice. Spores and cells were encapsulated into expanded clay aggregate to protect them from the harsh environment of fresh mortar. The viability of cells and spores after encapsulation was investigated. The 28- and 90-day mortar compressive strength was analysed. The healing performance of the resulting mortar samples that were cracked at the age of 28 and 90 days has also been observed. The results show that both cells and spores were still active after encapsulation. The yeast extract added to mortar containing spores decreased the compressive strength of the mortar compared to the reference sample. From the healing performance result, it seems that the spores are more suitable for mitigating microcracks in aged mortar, while cells are more suitable for mitigating early-age cracks in the mortar.

This study focuses on the evaluation of the efficiency of a low-cost macrocapsule, using commercially available pharmaceutical capsules with specific modifications, for self-healing concrete. The macrocapsules were developed by the Belgian Building Research Institute in a previous study. The healing agent is a resin based on alkyd-urethane, a low-cost commercial product, which was selected for its compatibility with concrete and shell, and also for the following reasons: resin release, adhesion to concrete, and reduction in capillary water absorption. After their manufacturing, the macrocapsules were carefully integrated within the concrete mix at 5 volume-%, and cubes and slabs for compressive and impact tests were cast. Small beams 160 x 40 x 40 mm3 containing each three capsules (placed 15 mm above the bottom surface) were tested for flexural strength and capillary water absorption. The effect of self-healing was evaluated by sorptivity test for two different crack mouth opening displacements of 0.5 mm and 0.9 mm. In both cases, the cracks were partially or completely healed, and the mechanical properties of the macrocapsule specimens were quite the same as the reference specimens. This demonstrates that the modified low-cost macrocapsules are sufficient to heal large cracks without losing the concrete mechanical properties.

The tracking of healing on concrete slabs where dense crack patterns are formed under bending is reported using Acoustic Emission (AE) and Ultrasound Pulse Velocity (UPV). Additively manufactured polymeric networks are designed to distribute a polyurethane agent through capillary actions and under pressure to the open cracks, formed in the slabs. It is shown that the crack pattern is controlled by the geometry of the vascular networks that are positioned near the steel reinforcement. The activation of both conventional linear and interlinked web-shaped networks is monitored by AE, however in both cases the load at which the initial cracks form is lower in series with embedded networks compared to the reference series, an indication of an overall weakening effect. The area where the healing agent circulates is larger (300x400 mm2) than past tests on beams, but only local healing is evident by UPV mapping. An indirect proof of cracks filling with stiffened agent is provided by the AE pencil-lead breaking test, as the amplitude recovery after healing can be linked to crack closure. This preliminary work evaluates the design of 3D printed vascular networks, but also explores the potential of AE and UPV as inspection tools in healing studies.

The capacity of hydrated lime to reabsorb CO2 as it hardens has made it a desirable replacement for cement to produce mortars with an overall lower environmental footprint. Still, research into lime-cement formulations remains limited, especially when it comes to their self-healing capacity. Some studies show that hydrated lime can improve self-healing in cement mixes, but addition rates are low. Here we present how high lime-cement ratios influence the self-healing capacity of lime mortars. Four mixes of increasing lime-cement ratios were cracked with tensile loading and placed under 1 hour wet, 23 hours dry cycles to stimulate self-healing. The mix design of 50 % lime-50 % cement volume (L50C50) showed self-healing abilities and was tested against a pure cement mixture (L0C100). Microscopy and water flow tests were performed at a cracking age of 7 days and then again after 28 days of healing in three regimes. Overall, submersion was the best healing regime for both L0C100 and L50C50 and crack self-healing was close to total (100 ± 1 % and 98 ± 6 %, respectively). Nevertheless, the water flow tests show that self-healing in L50C50 was in fact less efficient than that of the L0C100, achieving a 39 ± 21 % reduction in water flow versus 86 ± 11 %.

This study evaluated the mechanical properties and self-healing performance of cement mortar containing pulverized clinker, calcium sulfoaluminate (CSA), and Na2SO4. Mechanical properties of cement mortar were investigated by measuring compressive strength, and sealing efficiency were evaluated by a hydrostatic permeability test and a nitrogen gas diffusion test. Moreover, the healing products adhering to the cracks were visually observed with an optical microscope and a scanning electron microscope (SEM). As a result, incorporating pulverized clinker with mineral admixtures increased the 3- and 28-day strength by approximately 20%. There was a difference in the sealing efficiency depending on the evaluation method. The sealing efficiency of the gas diffusion test was underestimated due to the difference in characteristics according to the type of medium passing through the crack. Nevertheless, when the inorganic additive was mixed with cement mortar, CaCO3 precipitated as the healing product within 0.3 mm cracks and improved self-healing performance.

Capillary water absorption tests are widely used in uncracked cementitious materials to assess the quality and durability. Due to the easy execution of the test, it is also frequently used to assess the self-healing efficiency of self-healing concrete and mortar. It is established that the presence of a crack significantly increases the water uptake by a specimen. However, it is not known how the crack width, healing agents and mix composition influence the capillary water absorption. In this research, for cylindrical mortar specimens with four different crack widths, both a capillary water absorption test and water permeability were test were executed in order to investigate the relation between these two test methods. After the first round of testing, cracked specimens were healed manually with polyurethane and methyl methacrylate and the capillary absorption test was performed again to investigate the sensitivity of the test method to different degrees of crack healing. Furthermore, prismatic specimens were cast to investigate the influence of crack creation and geometry. It was found that the crack width does not have an influence on the capillary absorption rate. However, the crack width has a significant influence on the water flow through the crack. As expected, manual healing with polyurethane is better in comparison to the sealing of the crack mouth with methyl methacrylate.

Among the various possibilities to tackle the issue of concrete damage within its structural service life, the biomimetic approach has favoured the development of innovative solutions such as the use of 3D printed vascular networks suitably incorporated into concrete structural elements to inject and convey the most suitable healing agent upon crack occurrence. These systems, able to cope with damage of different intensities, may lead to improvements of the structure’s durability, through the closure of cracks, and a consequent reduction of the frequency of major maintenance activities. The present work investigates the environmental sustainability of the aforesaid self-healing technology through a Life Cycle Assessment (LCA) analysis. The attention has been also focused on the 3D printing process of the network due to the key role that it could play, in terms of environmental burdens, when upscaled to real-life size applications. The case study of a beam healed by means of polyurethane injected through the network and exposed to a chloride environment is reported to better predict the potential improvements in terms of overall durability and consequent sustainability within the pre-defined service life.

Vascular self-healing concrete is an innovative technology that can potentially improve the durability and longevity of concrete structures. However, limited research is available concerning this type of self-healing compared to intrinsic or capsule-based healing. As the rheology and curing properties of a healing agent can dictate the optimal design configuration of a vascular network, a series of testing procedures for evaluating healing agents is further explored. In this study, the suitability of various commercially available healing agents is considered using a vascular network system in mechanical loading and water absorption test set-ups. In this particular configuration, high sealing efficiencies were obtained for most of the healing agents used, and the polyurethanes and epoxy resin that were studied showed high load regain values. This work provides a testing methodology to select a healing agent in terms of its mechanical load regain, sealing efficiency, rheology, and curing properties, and can be used to determine a suitable healing agent for vascular healing applications.

The development of circular economy models for the construction sector brings important challenges and opportunities to research and particularly to make knowledge transfer, for example through public policies. Santiago de Cali, third major city of Colombia (South America), is developing a circular economy model policy, which is mainly based on waste valorisation. Among others, the model includes a family of eco-concrete products that replaces Portland cement by blast furnace slag and fly ash coming from local industries. Therefore, the aim of this research is to develop scientific based recommendations to stakeholders for the selection of different concrete products (i.e. beams, columns, slabs) using blast furnace slag and fly ash (eco-concretes). Considering that life cycle assessment (LCA) is the most employed tool for consolidating, comparing, and assessing sustainability impacts [1], the LCA of these concrete products for the design of a sustainable residential house was performed. The LCA software Building for Environmental and Economic Sustainability (BEES) developed by the National Institute of Standards and Technology (NIST) was selected for the study. Results include a discussion on the environmental impacts. Furthermore, a methodology for the selection of sustainable building materials is presented.

Application of self-healing concrete reduces the need for expensive maintenance and repair actions. However, the durability of self-healing concrete has only been scarcely investigated. Here, recent results are presented regarding the resistance of self-healing concrete to chloride ingress. For self-healing concrete with macro-encapsulated polyurethane, chloride profiles and electron probe microanalysis indicated that this mechanism was efficient to reduce the chloride penetration into the crack and from the crack into the concrete matrix [1]. Furthermore, the corrosion behaviour of reinforced concrete specimens subjected to cyclic exposure with a NaCl solution was studied [2]. The electrochemical measurements indicated that autonomous crack healing could significantly reduce the corrosion in the propagation stage. No visual damage could be detected on the rebars after 44 weeks of exposure. On the contrary, cracked specimens without integrated self-healing mechanism, reached a state of active corrosion after 10 weeks of exposure and after 26 weeks clear pitting damage was observed on the rebars. While self-healing by encapsulated polyurethane is complete after one day, bacteria-based products take several weeks to heal a 300 µm crack. Bacterial granules containing denitrifying cultures released nitrite as an intermediate metabolic product which protected the reinforcement during the crack healing process [3].

Many bonding failures between the substrate and repair mortar are attributed to too aggressive removal of the contaminated concrete and incorrect use of repair materials. To this end, in this study the effect of concrete removal techniques on substrates of different compositions and, as a result, on the bonding with repair mortar has been investigated. Substrate surfaces of different concrete compositions, micro-concrete (MC) and crushed stone concrete (CC), were treated by using three commonly used techniques: grit blasting (GB), jack-hammering (JH), and hydrodemolition/water-jetting (WJ). Automated Laser Measurements (ALM), sand patch tests and surface tensile strength measurements were applied to characterize the substrate surface. According to the results, the co-lateral effects of removal techniques such as WJ are dependent on the concrete mix composition. Moreover, WJ- and JH- treated samples achieved a lower surface tensile strength and bond strength compared to GB-treated slabs.

Super Absorbent Polymers (SAPs) have proven to be effective as a self-healing agent for regaining the liquid tightness of cracked concrete. This is due to their large swelling capacity which allows them to (partially) block cracks which are in contact with water or moisture. Additionally, they are able to release this water when the climate becomes drier, thereby promoting the autogenous healing capacity of the concrete matrix. The effect SAPs have on chloride migration into cracked concrete is still unknown. The swelling capacity of the SAPs might partially block the crack, but this does not necessarily mean that the chloride ingress into the crack is lower. Especially, since the porosity of concrete with SAPs is slightly higher when additional water is added to compensate for the loss in workability. This paper compares the chloride ingress in cracked mortar with and without SAPs. The specimens were saturated in a chloride solution during 1 or 5 weeks after which the chloride ingress could be visualised using silver nitrate. The specimens which healed prior to chloride saturation had a significantly lower chloride ingress. The SAPs were able to delay the chloride ingress, as well as limit the influence of the crack on the chloride ingress.

Cracks in reinforced concrete structures exposed to a marine environment or de-icing salts can cause major durability issues due do accelerated ingress of chloride ions. In this study, the influence of autonomous crack healing by means of encapsulated polyurethane on the chloride ingress perpendicular to cracks was evaluated. This was done quantitatively by determining perpendicular-to-crack chloride profiles by means of profile grinding followed by potentiometric titration and qualitatively through visualization of the chloride penetration front by means of the AgNO3 spray method. The resulting chloride profiles showed that the healing mechanism was able to reduce the chloride concentrations in the direct vicinity of the crack to a large extent and to reduce the perpendicular-to-crack chloride penetration, especially further away from the exposed surface. Visualization of the chloride penetration front showed some variation in crack healing. For some healed samples almost no additional chloride ingress was found compared to uncracked samples, others showed a slightly enhanced ingress at the crack location but less perpendicular-to-crack chloride penetration compared to untreated cracked samples. Generally, the reduced amount of chlorides present in the concrete matrix due to crack healing will enhance the durability and service life of concrete structures.

Pore structure characterization is a key aspect when studying the durability of cementitious materials. When supplementary cementitious materials (SCMs) are used changes in pore structure are expected, and the complexity of its analysis is increased. The purpose of this paper is to describe the pore structure variation of mortars with two types of SCMs: natural pozzolan from volcanic origin (NP), and limestone powder (LP). We tested mixes with cement replacements (in weight) of 20 % and 40% by NP, and 10 % and 20% by LP. To analyse the pore structure, two widely accepted and complementary techniques were applied: dynamic water vapour sorption (DVS) and mercury intrusion porosimetry (MIP). With the DVS data, the Barret-Joyner-Halenda (BJH) model was used for pore size distribution assessment. Calculations with the Dubinin-Radushkevich (DR) model were also made for the smallest pore size range. Tests were performed at 28 and 90 days. MIP and DVS allowed evaluating the effect of the studied SCMs on different pore size ranges. Both techniques provided comprehensive information over a wide range of pore sizes. The mix with 40 % of NP had the best evolution, showing a significant volume decrease in the mesopore range.

Over the last years, nanotechnology is getting more attractive and nanomaterials are being used more commonly in construction industry. One of these materials is nanosilica: the nano-sized, engineered form of silica fume. The replacement of cement by these nanoparticles is said to enhance both the mechanical performance and the durability of the concrete material. In this paper colloidal silica will be used, which is nanosilica in solution. A characterization of mortar mixtures containing different amounts of silica is done and a comparison is made with respect to a reference mixture.

The Lucas-Washburn equation is still being applied by a significant number of researchers for the modelling of water absorption in cementitious materials. A modern approach considers the extended Darcy’s law leading to the Richards equation instead. Three main assumptions are implied by the application of the Lucas-Washburn equation: the flow occurs in one direction only, the material is separated into one fully wet and one fully dry region, and pores are modelled as an assembly of parallel tubes of a particular radius. Its application to analyse experimental results allows defining these three assumptions as mere simplifications. Therefore, all the parameters comprised in the Lucas-Washburn model are apparent. Consequently, a very limited description of the transport properties of the material can be achieved. For many engineering purposes this would not be an issue, but for an intrinsic description of the material a more realistic model is required. This paper discusses the limitations of the Lucas-Washburn equation, and the advantages of the Richards equation regarding the modelling of water absorption in cementitious materials. The comparative analysis reveals the versatility of the Richards equation, with an approach that considers the material as a continuum and describes it through measurable parameters.

Concrete cracking can result in a significant reduction of the durability and the service life due to the ingress of aggressive agents Self-healing concrete is able to heal cracks without external intervention, thereby mitigating the need for manual repair. In the assessment of the healing efficiency of self-healing concrete the to-be-healed crack width is an important parameter and different researchers have emphasised that the variability of the crack width significantly hampers an accurate assessment of the healing efficiency. With two new crack control techniques the variability of the crack width was reduced in order to decrease the variability on the calculated healing efficiency. This paper reports on the application of these techniques for the assessment of self-healing mortar containing encapsulated polyurethane. The healing potential was investigated by looking at the degree of sealing using a water flow test setup. It was observed that by using a crack control technique the variability on the crack width can indeed be reduced. Nonetheless, this does not translate in an equivalent reduction on the variability of the healing efficiency. This indicates that other factors contribute to the variability of the healing efficiency.