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Different formulations of foaming polyurethane grout offer controlled expansion rates. This is crucial for precision in filling voids without exerting excessive pressure on surrounding structures, which could potentially cause damage. This study focuses on the impact of composition on the expansion performance of tailor-made polyurethane grouting materials. Initially, multiple unknown chemical reaction kinetic parameters were identified by combining free expansion tests, which involved measuring density and temperature changes, with the particle swarm optimization algorithm. A numerical simulation, integrating chemical kinetic models and fluid flow equations, was established to replicate the free expansion process of polyurethane grout in a cup, aligning with our experimental results. Subsequently, we analyzed the polymerization process of polyurethane grout with varying compositions to determine the effect of composition ratios on grout expansion. Our findings reveal that the expansion ratio of foaming polyurethane is predominantly influenced by the concentrations of physical and chemical foaming agents, followed by isocyanate concentration. Polyol, in contrast, exerts a relatively minor influence. Furthermore, the solubility of the physical foaming agent in the grout determines both its maximum allowable concentration and its maximum contribution to volume increase. This study provides valuable insights for the design and selection of polyurethane grout components tailored to diverse applications.

In shield tunneling projects, the selection of an accurate model to calculate the mechanical response of segment structure plays a crucial role in the design and cost of the project. The shell–spring and beam–spring models are two widely used methods for this purpose. However, it is still not clear how accurate and different these models are in calculation results under surcharge load. Therefore, to accurately calculate the internal forces and deformation of the segment structure and clarify the difference between the two models’ results, the shell–spring and beam–spring models were established based on a subway shield tunnel project in Zhengzhou city. The reliability of the models was verified by comparing and analyzing the differences in deformation results between the models and field measurements. Furthermore, the safety of the segment structure was evaluated according to the ultimate bearing capacity of the normal section. The results declare that: (1) In the shell–spring model, the internal force gradually reduces from the edges towards the center of the segment width, and the shield segment exhibits a prominent non-plane strain state. (2) The internal force of the beam–spring model is larger than that of the shell–spring model. The axial force difference between the two models is relatively small; meanwhile, there is a larger disparity in the bending moment. However, with an increase in surcharge loading, the discrepancy in internal forces between the two models gradually decreases. (3) The calculation results of the shell–spring model are close to the field-measured values and the shield tunnel model test values, which verifies the accuracy and reliability of the shell–spring model. Therefore, it is more reasonable to use the shell–spring model to calculate the mechanical response of the segment structure. (4) With an increase in surcharge loading, the safety of the shield tunnel decreases gradually. Therefore, surcharge loading above the shield tunnel should be reasonably controlled to meet the requirements of the normal use of the shield segment. This manuscript aims to provide a reference for the future design and optimization of the shield tunnels’ lining structure.

Under the policy of low carbon energy saving, higher requirements are put forward for magnesium smelting. As the mainstream magnesium smelting process, the Pidgeon process has the disadvantages of a long production cycle, high energy consumption and high carbon emission, which makes it difficult to meet the requirements of green environmental protection. This paper reviews the research progress on different magnesium smelting processes and further analyzes their energy consumption and carbon emissions. It is concluded that the standard coal required for the production of tons of magnesium using the relative vacuum continuous magnesium refining process is reduced by more than 1.5 t, the carbon emission is reduced by more than 10 t and the reduction cycle is shortened by more than 9.5 h. The process has the advantages of being clean, efficient and low-carbon, which provides a new way for the development of the magnesium industry.

The acidizing corrosion inhibitors reported so far have a poor effect on duplex stainless steel in high-temperature and high-concentration acid systems and cannot effectively inhibit the occurrence of selective corrosion. In this paper, a new acidizing corrosion inhibitor was designed, which was mainly composed of Mannich base and antimony salt. The inorganic substance in the corrosion inhibitor had good stability at high temperatures and could quickly form a complex with the metal matrix to enhance the binding ability. The organic substance can make up for the non-dense part of the inorganic film. The properties of developed corrosion inhibitors were analyzed by quantum chemical calculation, molecular dynamics simulation, and scanning electron microscopy. The results showed that a double-layer membrane structure could be constructed after adding the corrosion inhibitor, which could play a good role in blocking the diffusion of acid solution at high-temperature. The uniform corrosion rate of 2205 duplex stainless steel after adding acidizing corrosion inhibitor immersion in a simulated service condition (9 wt.% HCl + 1.5 wt.% HF + 3 wt.% CH3COOH + 4~6 wt.%) at 140 °C, 160 °C and 180 °C for a 4 h test is 6.9350 g·m−2·h−1, 6.3899 g·m−2·h−1 and 12.1881 g·m−2·h−1, respectively, which shows excellent corrosion inhibition effect and is far lower than that of the commonly accepted 81 g·m−2·h−1 and no selective corrosion could be detected.

Aluminum scandium nitride (Al1−xScxN) film has drawn considerable attention owing to its enhanced piezoelectric response for micro-electromechanical system (MEMS) applications. Understanding the fundamentals of piezoelectricity would require a precise characterization of the piezoelectric coefficient, which is also crucial for MEMS device design. In this study, we proposed an in situ method based on a synchrotron X-ray diffraction (XRD) system to characterize the longitudinal piezoelectric constant d33 of Al1−xScxN film. The measurement results quantitatively demonstrated the piezoelectric effect of Al1−xScxN films by lattice spacing variation upon applied external voltage. The as-extracted d33 had a reasonable accuracy compared with the conventional high over-tone bulk acoustic resonators (HBAR) devices and Berlincourt methods. It was also found that the substrate clamping effect, leading to underestimation of d33 from in situ synchrotron XRD measurement while overestimation using Berlincourt method, should be thoroughly corrected in the data extraction process. The d33 of AlN and Al0.9Sc0.1N obtained by synchronous XRD method were 4.76 pC/N and 7.79 pC/N, respectively, matching well with traditional HBAR and Berlincourt methods. Our findings prove the in situ synchrotron XRD measurement as an effective method for precise piezoelectric coefficient d33 characterization.

Suspenders are the crucial load-bearing components of long-span suspension bridges, and are sensitive to the repetitive vibrations caused by traffic load. The degradation of suspender steel wire is a typical corrosion fatigue process. Although the high-strength steel wire is protected by a coating and protection system, the suspender is still a fragile component that needs to be replaced many times in the service life of the bridge. Flexible central buckles, which may improve the wind resistance of bridges, are used as a vibration control measure in suspension bridges and also have an influence on the corrosion fatigue life of suspenders under traffic load. This study established a corrosion fatigue degradation model of high-strength steel wire based on the Forman crack development model and explored the influence of flexible central buckles on the corrosion fatigue life of suspenders under traffic flow. The fatigue life of short suspenders without buckles and those with different numbers of buckles was analyzed. The results indicate that the bending stress of short suspenders is remarkably greater than that of long suspenders, whereas the corrosion fatigue life of steel wires is lower due to the large bending stress. Bending stress is the crucial factor affecting the corrosion fatigue life of steel wires. Without flexible central buckles, short suspenders may have fatigue lives lower than the design value. The utilization of flexible central buckles can reduce the peak value and equivalent stress of bending stress, and the improved stress state of the short suspender considerably extends the corrosion fatigue life of steel wires under traffic flow. However, when the number of central buckles exceeds two, the increase in number does not improve the service life of steel wire.

To examine the pyrolysis and combustion characteristics of epoxy asphalt, the heat and smoke release characteristics were analyzed via TG-MS and cone calorimeter tests, and the surface morphology of residual carbon after pyrolysis and combustion was observed via scanning electron microscopy. The results showed that the smoke produce rate of epoxy asphalt was high in the early stage, and then sharply decreased. Moreover, the total smoke produced was close to that of base asphalt, and the surface of residual carbon presented an irregular network structure, which was rough and loose, and had few holes, however most of them existed in the form of embedded nonpenetration. The heat and smoke release characteristics of epoxy asphalt showed that it is not a simple fusion of base asphalt and epoxy resin. Instead, they promote, interact with, and affect each other, and the influence of epoxy resin was greater than that of base asphalt.

This paper investigated the influence of deep cryogenic treatments (DCT) on the tensile strength, elongation to fracture and conductivity of a deformation-processed Cu-Ni-Co-Si alloy. The tensile properties were measured using a mechanical testing machine. The conductivity was evaluated using a low-resistance tester. The microstructure and precipitated phases were analyzed using scanning electron microscopy (SEM), transmission electron microscopy (TEM), an energy dispersive spectrometer (EDS) and an X-ray diffractometer (XRD). The tensile strength, elongation to fracture and conductivity of the Cu-1.34Ni-1.02Co-0.61Si alloy before and after cold rolling at 47% reduction increased with increasing DCT time and tended to be stable at about 36 h. The microstructure became more uniform after the DCT. The grain size was refined and was smallest after DCT for 48 h. The DCT promoted the precipitation of the solid solution elements Ni, Co and Si from the Cu matrix to form many fine and evenly distributed 20–70 nm spherical second-phase particles in the grains and grain boundaries.

We investigate the electronic structure and work function modulation of α-Fe2O3 films by strain based on the density functional method. We find that the band gap of clean α-Fe2O3 films is a function of the strain and is influenced significantly by the element termination on the surface. The px and py orbitals keep close to Fermi level and account for a pronounced narrowing band gap under compressive strain, while unoccupied dz2 orbitals from conduction band minimum draw nearer to Fermi level and are responsible for the pronounced narrowing band gap under tensile strain. The spin polarized surface state, arising from localized dangling-bond states, is insensitive to strain, while the bulk band, especially for pz orbital, arising from extended Bloch states, is very sensitive to strain, which plays an important role for work function decreasing (increasing) under compressive (tensile) strain in Fe termination films. In particular, the work function in O terminated films is insensitive to strain because pz orbitals are less sensitive to strain than that of Fe termination films. Our findings confirm that the strain is an effective means to manipulate electronic structures and corrosion potential.