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A feasible approach was developed for the synthesis of ordered mesoporous SBA-15-type materials using coal fly ash (CFA) as raw material. In the proposed approach, CFA was, firstly, activated by subcritical water with the addition of NaOH, which allowed an efficient extraction of silicon species from CFA under strong acidic conditions at near room temperature. Subsequently, in the synthesis system, using silicon extraction solution as the silicon precursor, the introduction of anhydrous ethanol as a co-solvent effectively inhibited the polymerization of silanol species and promoted their collaborative self-assembly with surfactant molecules by enhancing the hydrogen bond interactions. The resultant SBA-15 material had a high purity, high specific surface area (1014 m2/g) and pore volume (1.08 cm3/g), and a highly ordered mesostructure, and, therefore, exhibited an excellent removal efficiency (90.5%) and adsorption capacity (160.8 mg/g) for methylene blue (MB) from simulated wastewater. Additionally, the generation of surface acid sites from the homogenous incorporation of Al atoms onto the mesoporous walls of SBA-15 combined with the perfect retention of the ordered mesostructure endowed the obtained Al-SBA-15 material with a further boost in the removal performance of MB. The MB removal efficiency can reach ~100%, along with a maximum adsorption capacity of 190.1 mg/g. [ABSTRACT FROM AUTHOR]

Designing the electronic structures of the van der Waals (vdW) heterostructures to obtain high-efficiency solar cells showed a fascinating prospect. In this work, we screened the potential of vdW heterostructures for solar cell application by combining the group III–VI MXA (M = Al, Ga, In and XA = S, Se, Te) and elementary group VI XB (XB = Se, Te) monolayers based on first-principle calculations. The results highlight that InSe/Te vdW heterostructure presents type-II electronic band structure feature with a band gap of 0.88 eV, where tellurene and InSe monolayer are as absorber and window layer, respectively. Interestingly, tellurene has a 1.14 eV direct band gap to produce the photoexcited electron easily. Furthermore, InSe/Te vdW heterostructure shows remarkably light absorption capacities and distinguished maximum power conversion efficiency (PCE) up to 13.39%. Our present study will inspire researchers to design vdW heterostructures for solar cell application in a purposeful way. [ABSTRACT FROM AUTHOR]

CNT-AlSi10Mg composites fabricated by SLM have drawn a lot attention in structural application due to its excellent strength, elasticity and thermal conductivities. A planetary ball milling method was used to prepare the carbon nanotube (CNT)-AlSi10Mg powders, and the CNT-AlSi10Mg composites were fabricated by selective laser melting (SLM). The density, microstructure and mechanical properties of CNT-AlSi10Mg composites were studied. The density of the test samples increased at first and then decreased with increasing scan speed. When the laser scan speed was 800 mm/s, the test sample exhibited the highest density. The hardness increased by approximately 26%, and the tensile strength increased by approximately 13% compared to those values exhibited by the unreinforced AlSi10Mg. The grains of CNT-AlSi10Mg composite are finer than that in the AlSi10Mg. The CNTs were distributed along the grain boundaries of AlSi10Mg. Some of the CNTs reacted with Al element and transformed into Al4C3 during SLM, while some of the CNTs still maintained their tubular structure. The combination of CNTs and Al4C3 has a significant improvement in mechanical properties of the composites through fine grain strengthening, second phase strengthening, and load transfer strengthening. [ABSTRACT FROM AUTHOR]

Ordered mesoporous Zr-Al composite oxide materials (denoted as OMZA-x) with different Zr contents have been synthesized by a solvent evaporation-inducing self-assembly procedure associated with a thermal treatment at 100 °C. A cooperative co-assembly process of amphiphilic triblock copolymer F127 molecules and inorganic hydroxyl species originated from the hydrolysis of Zr and Al precursors was proposed to explain the synthesis of OMZA-x. Compared to ordered mesoporous alumina prepared without introducing Zr species, the resultant OMZA-x exhibited a much more ordered mesostructure combined with a distinct increase in the pore volume and specific surface area. The highly homogenous doping of Zr into the mesopore walls together with the formation of Zr-O-Al bonds can effectively enhance the thermal and hydrothermal stability of OMZA-x. For instance, the ordered mesostructure and excellent textural properties of OMZA-6 prepared with the optimum atomic ratio of Al to Zr of 6 could be well maintained even after a high-temperature treatment at 1000 °C for 1 h or a hydrothermal treatment at 100 °C for 6 h. [ABSTRACT FROM AUTHOR]

A composite coating with enhanced mechanical properties including high hardness and excellent wear resistance was produced by laser cladding of mixed Ni45 and high-carbon ferrochrome powders on an ASTM 1045 steel substrate. Different quantities, ranging from 10 to 50 wt.% of high-carbon ferrochrome powder were added to the Ni45 powder to investigate the effect of mixture content on the cladding performance. The microstructure of the coatings were examined using scanning electron microscope, and the wear resistance was compared using a wear tester apparatus among the different cases. The results showed that the microstructure of the coating with 30 wt.% high-carbon ferrochrome content was mainly fine solid solution phase. With the increase of high-carbon ferrochrome content to 40 wt.% and above, cracks appeared on the cladding surface due to a large amount of chromium carbides formed during the process. The microhardness was enhanced remarkably by laser cladding the composite coating on the 1045 substrate, with 2.4 times higher than the hardness of the substrate when 30 wt.% high-carbon ferrochrome content was added. The best wear performance was achieved when the high-carbon ferrochrome content was 30 wt.%, demonstrating the smallest surface roughness and depth of wear marks. With further increased high-carbon ferrochrome content, microcracking and delamination were observed on the worn surfaces. [ABSTRACT FROM AUTHOR]

Hierarchically porous ZSM-5 was prepared by utilizing a two-step crystallization procedure with carbon–silica composites as precursors. The hierarchically porous zeolites obtained a regular mesoporous structure with aluminum incorporated into the carbon–silica composite frameworks. The carbon–silica composite zeolites were characterized by XRD, TEM, SEM, and nitrogen adsorption/desorption. As-prepared hierarchical zeolites were used in the 1,3,5-triisopropylbenzene (TIPB) cracking reaction and exhibited significantly high TIPB conversion, while the accessibility factors were also determined. [ABSTRACT FROM AUTHOR]

Based on the magneto-mechanical effect, the influence of crack size on stress evaluated with metal magnetic memory (MMM) technology was discussed in this paper. Based on equivalent theory, the regular rectangular grooves, with different widths and depths, were precut in the surface of an experimental sample for simulating surface crack, and a three dimensional electrically controlled displacement system was used to collect the Hp(y) signal of the sample under different stresses, and the fracture morphology was observed by using scanning electron microscopy (SEM). The results show that the influence of detection line on Hp(y) signal can be ignored; as stress increases, the Hp(y) signal turns counterclockwise around zero-crossing point and its mutation, corresponding to the location of groove, becomes distinct gradually. When groove depth is constant, the magnetic intensity gradient changes in the form of quadratic polynomial as groove width increases, and when the groove width is the same, the magnetic intensity gradient is a linear function of groove depth. When stress reaches the yield strength of the material, the magnetic intensity gradient decreases gradually as stress increases further, and the orientation of magnetic domain is seen as the main reason for that result. At last, the experimental results are discussed based on the piezomagnetic effect and leakage magnetic field theory of finite depth slit model, and the change of magnetic domain orientation is considered to be the main reason. [ABSTRACT FROM AUTHOR]

CO is a toxic gas discharged as a byproduct in tail gases from different industrial flue gases, which needs to be taken care of urgently. In this study, a CuCl/AC adsorbent was made by a facile route of physically mixing CuCl2 and Cu(HCOO)2 powder with activated carbon (AC), followed by heating at 533 K under vacuum. The samples were characterized by X-ray powder diffraction (XRD), inductively coupled plasma optical emission spectrometry (ICP-OES), N2 adsorption/desorption, and scanning electron microscopy (SEM). It was shown that Cu(II) can be completely reduced to Cu(I), and the monolayer dispersion threshold of CuCl on AC support is 4 mmol·g−1 AC. The adsorption isotherms of CO, CO2, CH4, and N2 on CuCl/AC adsorbents were measured by the volumetric method, and the CO/CO2, CO/CH4, and CO/N2 selectivities of the adsorbents were predicted using ideal adsorbed solution theory (IAST). The obtained adsorbent displayed a high CO adsorption capacity, high CO/N2, CO/CH4, and CO/CO2 selectivities, excellent ad/desorption cycle performance, rapid adsorption rate, and appropriate isosteric heat of adsorption, which made it a promising adsorbent for CO separation and purification. [ABSTRACT FROM AUTHOR]

Changes in the elasticity modulus of an epoxy molding compound (EMC), an electronic packaging polymer, under high-temperature air storage conditions, are discussed in this study. The elasticity modulus of EMC had two different compositions (different filling contents) under different temperatures (175, 200, and 225 °C) and aging times (100, 500, and 1500 h), which were analyzed by using dynamic mechanic analysis technology. The results revealed that the elasticity modulus increased in the thermal aging process, with an increase in the temperature and the aging time. The increments of the glassy and rubbery states were similar. However, the growing rate was significantly different, and the growth of the rubbery state was significantly higher than that of the glassy state. The filling content influenced the degree of aging of the materials significantly. At a low filling content, long-term aging under high temperatures completely changed the material structure, and the mechanical properties of the polymer were reduced. [ABSTRACT FROM AUTHOR]

A hierarchical zeolite Beta has been prepared by a feasible one-pot and one-step method, which is suitable for application in industrial production. The synthesis is a simple hydrothermal process with low-cost raw materials, without adding alcohol or adding seeds, and without aging, recrystallization, and other complex steps. The hierarchical zeolite Beta is a uniform nanocrystal (20–50 nm) aggregation with high external surface area (300 m2/g) and mesoporous volume (0.50 cm3/g), with the mesoporous structure composed of intercrystal and intracrystal pores. As an acid catalyst in benzylation of naphthalene with benzyl chloride, the hierarchical zeolite Beta has shown high activity in the bulky molecule reaction due to its introduction of mesostructure. [ABSTRACT FROM AUTHOR]