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Amphiphilic block copolymers-based aqueous color inks show great potential in the field of visual communication design. However, the conventional step-by-step chemistry employed to synthesize the amphiphilic block copolymers is intricate, with low yield and high economic and environmental costs. In this work, we present a novel method for preparing an amphiphilic AB di-block copolymer of PCL-b-PAA by employing a combined polymerization strategy that involves both cationic ring-opening polymerization (ROP) of the ε-caprolactone monomer and the reversible addition–fragmentation chain-transfer (RAFT) polymerization on the acrylic acid monomer simultaneously. The corresponding polycaprolactone (PCL) and polyacrylic acid (PAA) serve as the hydrophobic and hydrophilic units, respectively. The effectiveness of the amphiphilic AB di-block copolymer as the polymeric pigment dispersant for water-based color inks is evaluated. The amphiphilic AB di-block copolymer of PCL-b-PAA exhibits a molecular weight of 1400 g mol−1, which is consistent with the theoretical value and suitable for polymeric dispersant application. The high surface excess (Γmax) of the PCL-b-PAA in water indicates a densely packed molecular morphology at the water/air interface. Additionally, micelles can be stably formed in the aqueous PCL-b-PAA solution at very low concentrations by demonstrating a low CMC value of 10−4 wt% and a micelle dimension of approximately 30 nm. The model ink dispersion is prepared using organic dyes (Disperse Yellow 232) and the amphiphilic block copolymer of PCL-b-PAA. The dispersion demonstrates near-Newtonian behavior, which is highly favorable for the application as inkjet ink. Furthermore, the ink dispersion displays a low viscosity, making it particularly suitable for visual communication design and printing purposes. Moreover, the ink dispersion demonstrates an unimodal distribution of the particle size, with an average diameter of approximately 500 nm. It retains exceptional stability of dispersion and even conducts a thermal aging treatment at 60 °C for 5 days. This work presents a facile and efficient synthetic strategy and molecular design of AB di-block copolymer-based dispersants for dye dispersions. [ABSTRACT FROM AUTHOR]

To solve the problems of high cement dosage and poor fluidity of conventional cemented paste backfill (CPB) materials, the fluidity and strength properties of foam-cemented paste backfill (FCPB) were studied in combination. Based on determining the optimum contents of a foaming agent and a foam stabilizer, FCPB density was measured. To investigate the fluidity and strength of FCPB under different foam contents (0%, 5%, 10%, 15%, 20%, 25%, 30%, and 40%), different solid contents (75 wt.% and 77 wt.%), and different cement-tailing ratios (1:4 and 1:5), spread tests and unconfined compressive strength (UCS) tests were conducted. In addition, the FCPB microstructure was analyzed by scanning electron microscopy (SEM). The results indicate that the optimum combination dosages of sodium lauryl sulfate (K12) and sodium carboxymethyl cellulose (CMC) are 0.5 g/L and 0.2 g/L. The density decreases with the foam content (FC), but the fluidity and strength of the FCPB increase first and then decrease with the FC. In addition, the microstructure analysis explains the enhanced strength of FCPB by adding foam. These results contribute to further understanding the effect of foam content on the fluidity and strength of the FCPB. [ABSTRACT FROM AUTHOR]