1. Preparation of photochromic sol–gel composite films containing dodecaphosphotungstic acid
- Author
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Zhang, Tie Rui, Feng, Wei, Lu, Ran, Bao, Chun Yan, Li, Tie Jin, Zhao, Ying Ying, and Yao, Jian Nian
- Subjects
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PHOTOCHROMIC materials , *CHARGE transfer , *TUNGSTIC acid - Abstract
A novel photochromic gel film was prepared through entrapping 12-phosphotungstic acid (PWA) into a kind of inorganic–organic matrix co-hydrolyzed from tetraethylorthosilicate (TEOS) and 3-aminopropyltriethoxysilane (APTES). Infrared (IR) spectra revealed that the Keggin structure characteristic of
PW12O403− anions was present in the amine-functionalized silica gel skeleton and PWA interacted withR-NH3+ cations strongly. The amorphous state of the gel film was proved by X-ray diffraction (XRD) pattern. The gel film exhibited reversible photochromicity. Irradiated with ultraviolet light, the transparent film changes from colorless to blue. Then, bleaching occurs when the film is in contact with air or O2 in the dark. [Copyright &y& Elsevier]- Published
- 2003
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