Tang, Yan, Ou, Qingzhu, Zhong, Yanjun, Liu, Heng, Zhong, Benhe, Guo, Xiaodong, and Chen, Mingzhe
Porous structure Li 3 V 2 (PO 4 ) 3 /C composite has been successfully prepared through a facile PVP-assisted sol-gel method, following by high temperature sintering. SEM and TEM results show that the Li 3 V 2 (PO 4 ) 3 /C composite has a pore structure with a carbon coating of about 6 nm. In the voltage range of 3.0–4.5 V, discharge capacities of 130.3, 125.1, 118.3, 113.5 and 108.0 mAh g −1 can be delivered at 0.1, 1, 5, 10 and 20 C, respectively. Moreover, it exhibits discharge capacities of 130.4 and 177.8 mAh g −1 at 1 C in the voltage range of 3.0–4.8 V and 1.5–4.5 V, respectively. These results demonstrate that the rate capability and cyclability of Li 3 V 2 (PO 4 ) 3 /C can be ameliorated by the porous structure. [ABSTRACT FROM AUTHOR]