1. One-step green synthesis of N-doped hierarchical porous carbon from glycine for high-performance symmetric supercapacitor.
- Author
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Zhang, Feng, Guo, Dongxiang, and Du, Guixiang
- Subjects
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SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *DOPING agents (Chemistry) , *POROUS materials synthesis , *GLYCINE , *ENERGY density , *POWER density - Abstract
N-doped hierarchical porous carbon as an excellent electrode material in symmetric supercapacitor is fabricated by a facile and green method. [Display omitted] • N-doped porous carbon is prepared from one-step pyrolysis of glycine and Na 2 CO 3. • It exhibits a high capacitance of 207 F/g at 20 A/g in a symmetric supercapacitor. • 99.95% of initial capacitance remains after 10,000 cycles at 5 A/g. • A high energy density of 28.8 Wh/kg is obtained at a power density of 20 KW/kg. N-doped hierarchical porous carbon (NHPC) was facilely fabricated by a one-step pyrolysis of glycine and water-soluble Na 2 CO 3 , which is employed as a renewable water-soluble template without additional corrosive activating reagent. Benefiting from the hierarchical porous structure, high specific surface area (2735 m2 g−1) and the suitable nitrogen content of 3.84 at%, the obtained porous carbon exhibits a high specific capacitance (C sp) of 267 F g−1 at 0.2 A g−1 in a three-electrode system and 201 F g−1 at 0.2 A g−1 in the symmetric supercapacitor. More importantly, it shows an impressive rate capability of 102 % retention at 20 A g−1, outstanding cycling stability with 99.95 % of capacitance retention at 5 A g−1 after 10,000 cycles and a high energy density of 28.8 Wh kg−1 at a power density of 20 KW kg−1 in the symmetric supercapacitor. The results indicate that the synthesized NHPC obtained from this simple synthesis method would be an effective electrode material for symmetric supercapacitors, and this eco-friendly and easily scaled-up approach would provide a valuable strategy for the synthesis of porous carbon materials. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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