1. A facile one-step route to nanocrystalline TiB2 powders
- Author
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Chen, Luyang, Gu, Yunle, Qian, Yitai, Shi, Liang, Yang, Zeheng, and Ma, Jianhua
- Subjects
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NANOCRYSTALS , *TITANIUM diboride , *CHEMICAL reactions , *X-rays , *OPTICAL diffraction - Abstract
Nanocrystalline titanium diboride (TiB2) has been prepared by the reaction of TiCl4 with NaBH4 in the temperature range of 500–700 °C in an autoclave. X-ray powder diffraction (XRD) patterns can be indexed as hexagonal TiB2 with the lattice constants of
a=3.032 andc=3.229 A˚. Transmission electron microscopy (TEM) image shows particle morphology, with average size of 15 nm for the powder obtained at 600 °C. Selected area electron diffraction (SAED) pattern confirms the prepared hexagonal TiB2. The oxidation behavior of TiB2 is studied by thermogravimetric analysis (TGA) and differential thermal analysis (DTA). [Copyright &y& Elsevier]- Published
- 2004
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