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The tribological properties of Al-Li alloys impact the reliability of components used in different industrial sectors. In this research, the effect of normal load on friction and wear properties of the extruded spray-formed 2195-T6 Al-Li alloy is investigated by using a pin-on-disk tester. Through the microstructure of the friction subsurface, it is evaluated that the friction coefficient of 2195 alloy decreases from 0.408 to 0.306 by increasing load (25 N to 150 N), while the wear rate increases exponentially. It is also analyzed that a mild-severe wear transition occurs between 100 N and 125 N and the main wear mechanism gradually shifts from abrasive wear and oxidative wear to delamination wear (25 N ∼ 100 N), and finally attains the state of severe plastic deformation (125 N ∼ 150 N). Under the action of normal load and friction shearing force, the deformation layer in the subsurface increases from 3 μ m to 43 μ m with increasing load, and the accumulation of strain leads to cracks and holes.