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Your search keyword '"Mikhail M. Il’in"' showing total 3 results
Start Over Author "Mikhail M. Il’in" Journal mendeleev communications
3 results on '"Mikhail M. Il’in"'

1. Palladium complex with tetrahydronaphthyl-substituted diimine ligand as a catalyst for polymerization of norbornenes and diazoacetates

Author

Mikhail M. Il’in, Zoya B. Khesina, Ivan V. Nazarov, Elizaveta K. Melnikova, Maxim V. Bermeshev, Konstantin V. Potapov, and Evgeniya V. Bermesheva

Subjects
chemistry.chemical_compound, chemistry, Polymerization, Ligand, Polymer chemistry, Glyoxal, chemistry.chemical_element, General Chemistry, Diimine, Derivative (chemistry), Catalysis, Palladium, Norbornene
Abstract

New methylpalladium chloride complex with bulky N,N'-bis(1,2,3,4-tetrahydro-1-naphthyl)-substituted glyoxal diimine ligand was obtained. This complex was found to be an efficient catalyst for vinyl-addition polymerization of norbornene derivative and for polymerization of a diazoacetate, giving polycarbenes with side polar functionalities.

Published
2021
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2. Synthesis, structure and thermal properties of propylene oxide–carbon dioxide–L-lactide terpolymers

Author

Z. N. Nysenko, Galina G. Nikiforova, Ernest Said-Galiev, Yakov E. Belevtsev, Mikhail M. Il’in, Mikhail I. Buzin, and A. M. Sakharov

Subjects
chemistry.chemical_compound, chemistry, Adipate, Polymer chemistry, Carbon dioxide, Propylene carbonate, chemistry.chemical_element, General Chemistry, Propylene oxide, Zinc, Carbon-13 NMR, Spectroscopy, Catalysis
Abstract

Terpolymers with different L-lactic acid contents in the poly(propylene carbonate) chain were synthesized by the terpolymerization of carbon dioxide, propylene oxide and L-lactide, catalyzed by zinc adipate. The terpolymerization products were characterized by 1 H and 13 C NMR, 2D { 1 H- 13 C} HMBC and FT-IR spectroscopy, DSC, TGA and GPC.

Published
2014
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3. Regioselective aza-Michael addition of azoles to 4-(diphenylphosphoryl)but-3-en-2-one

Author

Mikhail M. Il’in, Valery K. Brel, Natalia G. Kolotyrkina, M. A. Galkina, E. I. Goryunov, G. V. Bodrin, Aleksandra S. Sherstneva, Konstantin A. Kochetkov, I. B. Goryunova, and Jumakan S. Urmambetova

Subjects
Bicyclic molecule, 010405 organic chemistry, Chemistry, Stereochemistry, Regioselectivity, General Chemistry, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Adduct, Catalysis, chemistry.chemical_compound, Yield (chemistry), Michael reaction, Imidazole
Abstract

Aza-Michael reaction of ( E )-4-(diphenylphosphoryl)but-3-en-2-one with mono- and bicyclic nitrogen heterocycles proceeds regioselectively in the absence of catalysts to give the corresponding s-diphenylphosphoryl-b-azahetarylalkanones. Its reaction with imidazole in the presence of chiral organocatalysts affords the corresponding enantiomerically enriched adduct in higher yield.

Published
2016
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