1. Hydrothermal conversion of Fe2O3/SiO2 spheres into Fe2O3/Silicalite-1 nanowires: Synthesis, characterization, and catalytic properties.
- Author
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Xie, Pengfei, Chen, Lifeng, Ma, Zhen, Huang, Chengyun, Huang, Zhiwei, Yue, Yinghong, Hua, Weiming, Tang, Yi, and Gao, Zi
- Subjects
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IRON oxide nanoparticles , *THERMAL analysis , *ENERGY conversion , *SILICA , *SYNTHESIS of nanowires , *CALCINATION (Heat treatment) , *SPRAY drying , *CATALYSIS - Abstract
Fe 2 O 3 nanoparticles were dispersed onto SiO 2 by impregnating amorphous SiO 2 spheres with Fe(NO 3 ) 3 followed by spray drying and calcination. Interestingly, the amorphous SiO 2 spheres in the sample could be converted into Silicalite-1 nanowires after being hydrothermally treated in the presence of a mixture of ethylenediamine and triethylamine (dual templates) for over 4 days, whereas the Fe 2 O 3 nanoparticles were still highly dispersed on the formed Silicalite-1 nanowires. Meanwhile, a fraction of Fe(III) species entered the zeolitic framework. Relevant characterization was conducted using X-ray fluorescence (XRF), N 2 adsorption–desorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet–visible (UV–Vis) spectroscopy, electron paramagnetic resonance (ESR), X-ray photoelectron spectroscopy (XPS), and H 2 -temperature-programmed reduction (H 2 -TPR). The catalytic properties of the samples were studied using CO oxidation, N 2 O decomposition, and selective reduction of NO as probe reactions. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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