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Ultra-thin flakes of layered materials have recently been attracting widespread research interest due to their exotic properties. In this work, we study the optoelectronic response of a hybrid of two such materials – graphene and MoS2. Our devices consist of mechanically exfoliated graphene flakes transferred on top of similarly exfoliated MoS2. The electrical response of the hybrid is studied in the presence of white light. We show that the four-point resistance of graphene is modulated in the presence of light. This effect is observed to be a strong function of gate voltage. We have also extended our studies to CVD (chemical vapor deposition) - grown graphene transferred onto MoS2 which show qualitatively similar features, thereby attesting to the scalability of the device architecture.

Molecular wires of charge transfer molecules were formed by co-evaporating the 7 7 8 8-Tetracyanoquinodimethane [TCNQ] (acceptor) and Tetrathiafulvalene [TTF] (donor) molecules across prefabricated metal electrodes. Molecular wires of TTF TCNQ were also formed by evaporating single complex of TTF:TCNQ across prefabricated metal electrodes The prefabricated metal electrodes were made using electron beam lithography on SiO2 and glass cover slip substrates. Even though TTF: TCNQ wires grown from both co-evaporation and evaporation techniques show semiconductor like behavior in temperature dependence of resistance they show different activation energies due the difference in stoichiometry of TTF and TCNQ.