1. Boron Nitride–Graphene Nanocapacitor and theOrigins of Anomalous Size-Dependent Increase of Capacitance.
- Author
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Shi, Gang, Hanlumyuang, Yuranan, Liu, Zheng, Gong, Yongji, Gao, Weilu, Li, Bo, Kono, Junichiro, Lou, Jun, Vajtai, Robert, Sharma, Pradeep, and Ajayan, Pulickel M.
- Subjects
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BORON nitride , *GRAPHENE , *NANOPARTICLES , *DIELECTRIC materials , *CHEMICAL yield , *QUANTUM capacitance - Abstract
Conventionalwisdom suggests that decreasing dimensions of dielectricmaterials (e.g., thickness of a film) should yield increasing capacitance.However, the quantum capacitance and the so-called “dead-layer”effect often conspire to decrease the capacitance of extremely smallnanostructures, which is in sharp contrast to what is expected fromclassical electrostatics. Very recently, first-principles studieshave predicted that a nanocapacitor made of graphene and hexagonalboron nitride (h-BN) films can achieve superior capacitor properties.In this work, we fabricate the thinnest possible nanocapacitor system,essentially consisting of only monolayer materials: h-BN with grapheneelectrodes. We experimentally demonstrate an increase of the h-BNfilms’ permittivity in different stack structures combinedwith graphene. We find a significant increase in capacitance belowa thickness of ∼5 nm, more than 100% of what is predicted byclassical electrostatics. Detailed quantum mechanical calculationssuggest that this anomalous increase in capacitance is due to thenegative quantum capacitance that this particular materials systemexhibits. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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