1. Ultrasonic-assisted synthesis and DNA interaction studies of two new Ru complexes; RuO2 nanoparticles preparation
- Author
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Mao-Lin Hu, Jian-Ping Liu, Fahime Bigdeli, Jun-Jie Xue, and Ali Morsali
- Subjects
Nanostructure ,Absorption spectroscopy ,Sonication ,Thermal decomposition ,Biomedical Engineering ,Medicine (miscellaneous) ,chemistry.chemical_element ,Nanoparticle ,Bioengineering ,02 engineering and technology ,Development ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Photochemistry ,01 natural sciences ,0104 chemical sciences ,Ruthenium ,chemistry ,X-ray crystallography ,Molecule ,General Materials Science ,0210 nano-technology - Abstract
Aim: To study of the interactions of two new ruthenium(II) complexes (C1 and C2) with calf thymus (CT)-DNA; production of RuO2 nanoparticles using the complexes precursor. Materials & methods: Complex C1 was characterized by x-ray crystallography. The binding of the complexes with (CT)-DNA was studied using techniques that include electronic absorption spectra, fluorescence and redox behavior. The preparation of RuO2 nanoparticles was carried out by thermal decomposition. Results: The interaction mode of DNA with complexes is the type of electrostatic. It was revealed that sonication of the samples, before thermal decomposition, has been affected the morphologies and sizes of the resulting nanoparticles. Conclusion: The complexes are capable of interaction with DNA molecules and they have a good potential to prepare nanostructures.
- Published
- 2018
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