1. Hydrogen sensing properties of nanocomposite graphene oxide/Co-based metal organic frameworks (Co-MOFs@GO)
- Author
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Somayeh Fardindoost, Fatemeh Razi Astaraei, Azam Iraji zad, and Shadie Hatamie
- Subjects
Materials science ,Hydrogen ,Inorganic chemistry ,Oxide ,chemistry.chemical_element ,Bioengineering ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Hydrogen sensor ,law.invention ,chemistry.chemical_compound ,law ,General Materials Science ,Electrical and Electronic Engineering ,Graphene oxide paper ,Nanocomposite ,Graphene ,Mechanical Engineering ,General Chemistry ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,chemistry ,Chemical engineering ,Mechanics of Materials ,Metal-organic framework ,0210 nano-technology ,Platinum - Abstract
This paper reports on hydrogen sensing based graphene oxide hybrid with Co-based metal organic frameworks (Co-MOFs@GO) prepared by the hydrothermal process. The texture and morphology of the hybrid were characterized by powder x-ray diffraction, scanning electron microscopy and Brunauer-Emmett-Teller analysis. Porous flower like structures assembled from Co-MOFs and GO flakes with sufficient specific surface area are obtained, which are ideal for gas molecules diffusion and interactions. Sensing performance of Co-MOFs@GO were tested and also improved by sputtering platinum (Pt) as a catalyst. The Pt-sputtered Co-MOFs@GO show outstanding hydrogen resistive-sensing with response and recovery times below 12 s at 15 °C. Also, they show stable, repeatable and selective responses to the target gas which make it suitable for the development of a high performance hydrogen sensor.
- Published
- 2017
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