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Your search keyword '"Aldo Mozzanica"' showing total 3 results
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3 results on '"Aldo Mozzanica"'

1. Metastable water at several compression rates and its freezing kinetics into ice VII

Author

Charles M. Pépin, Ramesh André, Florent Occelli, Florian Dembele, Aldo Mozzanica, Viktoria Hinger, Matteo Levantino, and Paul Loubeyre

Subjects
Science
Abstract

Abstract Water can be dynamically over-compressed well into the stability field of ice VII. Whether water then transforms into ice VII, vitreous ice or a metastable novel crystalline phase remained uncertain. We report here the freezing of over-compressed water to ice VII by time-resolved X-ray diffraction. Quasi-isothermal dynamic compression paths are achieved using a dynamic-piezo-Diamond-Anvil-Cell, with programmable pressure rise time from 0.1 ms to 100 ms. By combining the present data set with those obtained on various ns-dynamical platforms, a complete evolution of the solidification pressure of metastable water versus the compression rate is rationalized within the classical nucleation theory framework. Also, when crystallization into ice VII occurs in between 1.6 GPa and 2.0 GPa, that is in the stability field of ice VI, a structural evolution over few ms is then observed into a mixture of ice VI and ice VII that seems to resolve apparent contradictions between previous results.

Published
2024
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2. Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

Author

Grigory Smolentsev, Christopher J. Milne, Alexander Guda, Kristoffer Haldrup, Jakub Szlachetko, Nicolo Azzaroli, Claudio Cirelli, Gregor Knopp, Rok Bohinc, Samuel Menzi, Georgios Pamfilidis, Dardan Gashi, Martin Beck, Aldo Mozzanica, Daniel James, Camila Bacellar, Giulia F. Mancini, Andrei Tereshchenko, Victor Shapovalov, Wojciech M. Kwiatek, Joanna Czapla-Masztafiak, Andrea Cannizzo, Michela Gazzetto, Mathias Sander, Matteo Levantino, Victoria Kabanova, Elena Rychagova, Sergey Ketkov, Marian Olaru, Jens Beckmann, and Matthias Vogt

Subjects
Science
Abstract

OLED materials based on thermally activated delayed fluorescence have promising efficiency. Here, the authors investigate an organometallic multicore Cu complex as luminophore, by pump-probe X-ray techniques at three different facilities deriving a complete picture of the charge transfer in the triplet excited state.

Published
2020
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3. Strain wave pathway to semiconductor-to-metal transition revealed by time-resolved X-ray powder diffraction

Author

Simon Ebner, Majed Chergui, Hervé Cailleau, Paul Beaud, Henrik T. Lemke, Eric Collet, Gerhard Ingold, Alexei Bosak, Andrej Babic, Dmitry Ozerov, S. Vetter, Laurent Cario, Roman Bertoni, Laurent Guérin, Pavle Juranić, Michael Wulff, Giulia F. Mancini, Vincent Esposito, T. Zmofing, Alexander Roland Oggenfuss, Aldo Mozzanica, Shin-ichi Ohkoshi, Yunpei Deng, Maciej Lorenc, Ivan Usov, Serhane Zerdane, Matteo Levantino, Akos Schreiber, Marco Cammarata, Roman Mankowsky, Elzbieta Trzop, Rolf Follath, P. Böhler, Céline Mariette, S. Redford, C. Svetina, Olivier Hernandez, Leonardo Sala, A. Volte, X. Dong, L. Patthey, Hiroko Tokoro, V. Ta Phuoc, B. Lépine, A. Keller, Etienne Janod, Institut de Physique de Rennes (IPR), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Institut des Matériaux Jean Rouxel (IMN), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN), GREMAN (matériaux, microélectronique, acoustique et nanotechnologies) (GREMAN - UMR 7347), Institut National des Sciences Appliquées - Centre Val de Loire (INSA CVL), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Université de Tours (UT)-Centre National de la Recherche Scientifique (CNRS), The University of Tokyo (UTokyo), Université de Tsukuba = University of Tsukuba, SwissFEL, Paul Scherrer Institut, SLAC National Accelerator Laboratory (SLAC), Stanford University, Ecole Polytechnique Fédérale de Lausanne (EPFL), European Synchrotron Radiation Facility (ESRF), IM‐LED LIA, Université de Rennes (UR)-Centre National de la Recherche Scientifique (CNRS), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Nantes (UN)-Université de Nantes (UN)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Tours (UT)-Institut National des Sciences Appliquées - Centre Val de Loire (INSA CVL), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), ANR-16-CE30-0018,ELASTICA,Cooperativité Elastique Photo-Induite dans des Matériaux Bistables avec Changement de Volume(2016), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Université de Tours-Centre National de la Recherche Scientifique (CNRS)

Subjects
Diffraction, Phase transition, Materials science, Electronic properties and materials, Bistability, Science, FOS: Physical sciences, General Physics and Astronomy, Physics::Optics, Applied Physics (physics.app-ph), 02 engineering and technology, 01 natural sciences, General Biochemistry, Genetics and Molecular Biology, Article, Condensed Matter::Materials Science, 0103 physical sciences, Physics::Atomic and Molecular Clusters, [CHIM]Chemical Sciences, 010306 general physics, [PHYS]Physics [physics], Condensed Matter - Materials Science, Multidisciplinary, Condensed matter physics, Materials Science (cond-mat.mtrl-sci), Physics - Applied Physics, General Chemistry, Acoustic wave, 021001 nanoscience & nanotechnology, 3. Good health, Phase transitions and critical phenomena, Picosecond, Femtosecond, 0210 nano-technology, Ultrashort pulse, Powder diffraction
Abstract

Thanks to the remarkable developments of ultrafast science, one of today's challenges is to modify material state by controlling with a light pulse the coherent motions that connect two different phases. Here we show how strain waves, launched by electronic and structural precursor phenomena, determine a macroscopic transformation pathway for the semiconducting-to-metal transition with large volume change in bistable Ti$_3$O$_5$ nanocrystals. Femtosecond powder X-ray diffraction allowed us to quantify the structural deformations associated with the photoinduced phase transition on relevant time scales. We monitored the early intra-cell distortions around absorbing metal dimers, but also long range crystalline deformations dynamically governed by acoustic waves launched at the laser-exposed Ti$_3$O$_5$ surface. We rationalize these observations with a simplified elastic model, demonstrating that a macroscopic transformation occurs concomitantly with the propagating acoustic wavefront on the picosecond timescale, several decades earlier than the subsequent thermal processes governed by heat diffusion., 30 pages (including supplementary text), 5 main figures, 9 supplementary figures; corrected author list

Published
2020
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